Synthesis and electrochemical performance of Li2FeSiO4/C cathode material using ascorbic acid as an additive

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• 作者：Ming Li (1) (2)
  Lu-Lu Zhang (1) (3)
  Xue-Lin Yang (1)
  Yun-Hui Huang (4)
  Hua-Bin Sun (1)
  Shi-Bing Ni (1)
  Hua-Chao Tao (1)
  
  1. College of Materials and Chemical Engineering ; Hubei Provincial Collaborative Innovation Center for New Energy Microgrid ; China Three Gorges University ; 8 Daxue Road ; Yichang ; 443002 ; Hubei ; China
  2. College of Mechanical & Power Engineering ; China Three Gorges University ; 8 Daxue Road ; Yichang ; 443002 ; Hubei ; China
  3. CAS Key Laboratory of Materials for Energy Conversion ; Shanghai Institute of Ceramics ; Chinese Academy of Sciences ; Shanghai ; 200050 ; China
  4. School of Materials Science and Engineering ; State Key Laboratory of Material Processing and Die & Mould Technology ; Huazhong University of Science and Technology ; 1037 Luoyu Road ; Wuhan ; 430074 ; Hubei ; China
  
• 关键词：Lithium ; ion battery ; Cathode ; Lithium iron silicate ; Ascorbic acid
• 刊名：Journal of Solid State Electrochemistry
• 出版年：2015
• 出版时间：February 2015
• 年：2015
• 卷：19
• 期：2
• 页码：415-421
• 全文大小：1,250 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Analytical Chemistry
  Industrial Chemistry and Chemical Engineering
  Characterization and Evaluation Materials
  Condensed Matter
  Electronic and Computer Engineering
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1433-0768

文摘

Carbon-coated Li2FeSiO4 composite (LFS/C-AA) was synthesized via a refluxing-assisted solid-state reaction by using ascorbic acid as additive and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, galvanostatic charge/discharge measurements, and electrochemical impedance spectra (EIS) tests. The results show that ascorbic acid can to some extent prohibit the oxidation of Fe2+ during the synthesis process, and the pyrolytic carbon from ascorbic acid shows higher electronic conductivity and improves the degree of graphitization of residual carbon in the LFS/C-AA composite. Compared with LFS/C prepared without ascorbic acid, LFS/C-AA displays better electrochemical performance. The desirable property is attributed to the reduced particle size, the enhanced electronic conductivity, and the improved diffusion coefficient of lithium ions.