Recovery of Silver and Gold from Copper Anode Slimes

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• 作者：Ailiang Chen (1)
  Zhiwei Peng (2) (3)
  Jiann-Yang Hwang (3) (4)
  Yutian Ma (5)
  Xuheng Liu (1)
  Xingyu Chen (1)
  
  1. School of Metallurgy and Environment ; Central South University ; Changsha ; 410083 ; Hunan ; China
  2. School of Minerals Processing and Bioengineering ; Central South University ; Changsha ; 410083 ; Hunan ; China
  3. Department of Materials Science and Engineering ; Michigan Technological University ; Houghton ; MI ; 49931 ; USA
  4. Advanced Materials R&D Center of WISCO ; Beijing ; 102211 ; China
  5. Jinchuan Group Co. Ltd. ; Jinchang ; 737104 ; Gansu ; China
  
• 刊名：JOM Journal of the Minerals, Metals and Materials Society
• 出版年：2015
• 出版时间：February 2015
• 年：2015
• 卷：67
• 期：2
• 页码：493-502
• 全文大小：914 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Metallic Materials
  Nanotechnology
  Crystallography
  
• 出版者：Springer Boston
• ISSN：1543-1851

文摘

Copper anode slimes, produced from copper electrolytic refining, are important industrial by-products containing several valuable metals, particularly silver and gold. This article provides a comprehensive overview of the development of the extraction processes for recovering silver and gold from conventional copper anode slimes. Existing processes, namely pyrometallurgical processes, hydrometallurgical processes, and hybrid processes involving the combination of pyrometallurgical and hydrometallurgical technologies, are discussed based in part on a review of the form and characteristics of silver and gold in copper anode slimes. The recovery of silver and gold in pyrometallurgical processes is influenced in part by the slag and matte/metal chemistry and related characteristics, whereas the extraction of these metals in hydrometallurgical processes depends on the leaching reagents used to break the structure of the silver- and gold-bearing phases, such as selenides. By taking advantage of both pyrometallurgical and hydrometallurgical techniques, high extraction yields of silver and gold can be obtained using such combined approaches that appear promising for efficient extraction of silver and gold from copper anode slimes.