Kinetics and mechanism of the oxidation of diaquabis(1,10-phenanthroline) iron(II) by periodate in aqueous and micellar media

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• 作者：Hassan A. Ewais ; Abdulla Y. Obaid
• 刊名：Transition Metal Chemistry
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：41
• 期：3
• 页码：357-362
• 全文大小：535 KB
• 参考文献：1.Sariego R, Farias L, Moya SA (1997) Polyhedron 16:3847CrossRef
  2.Johann TW, Barton JK (1996) Philos Trans R Soc Lond A 354:299CrossRef
  3.Chalk SJ, Tyson JF (1994) Anal Chem 66:660CrossRef
  4.Woodward MP, Youngy WW, Bloodgood RA (1985) J Immunol Method 78:143CrossRef
  5.Symons MCR (1955) J Chem Soc 2794. doi:10.​1039/​jr9550002794
  6.EL-Ziri FR, Sulfab Y (1977) Inorg Chim Acta 25:15CrossRef
  7.Ewais HA, Ismail IM, Qusti AH, Abdel-Khalek AA (2013) Oxid Commun 36:601
  8.Ewais HA, Ismail IM (2013) J Chem Sci 125:1151CrossRef
  9.Abdel-Khalek AA, Ismail IMI, Nagdy MA, Ewais HA (2012) Oxid Commun 35:327
  10.Ewais HA, Habib MA, Elroby SAK (2010) Trans Met Chem 35:73CrossRef
  11.Ewais HA, Nagdy MA, Abdel-Khalek AA (2012) Trans Met Chem 37:525CrossRef
  12.Abdel-Khalek AA, Mohamed AA, Ewais HA (1999) Trans Met Chem 24:233CrossRef
  13.Ewais HA, Ismail IM, Ahmed SA, Abdel-Khalek AA (2014) Oxid Commun 37:209
  14.Sklarz B (1967) Organic chemistry of periodates. Q Rev Chem Soc 21:3–28CrossRef
  15.Kasim AY, Sulfab Y (1981) Inorg Chem 20:506CrossRef
  16.Kustin K, Lieberman CE (1964) J Phys Chem 68:3869CrossRef
  17.Sulfab Y (1976) J Inorg Nucl Chem 38:2271CrossRef
  18.Hussin MA, Sulfab Y (1982) Trans Met Chem 7:181CrossRef
  19.Pelizzetti E, Pramauro E (1979) Inorg Chem 18:882CrossRef
  20.Wilkins RG (1991) Kinetics and mechanism of reactions of transition metal complexes, 2nd edn. VCH Publishers Inc, New YorkCrossRef
  21.Lever ABP (1984) Inorganic electronic spectroscopy. Elsevier, Amsterdam
  22.Hadinec I, Jensovsky L, Linek A, Synecek V (1960) Naturwiss 47:377CrossRef
  23.Ray P (1957) Inorg Synth 5:201
  24.Crouthamel CE, Hayes AM (1951) J Am Chem Soc Jpn 73:82CrossRef
  25.Kassim AY, Sulfab Y (1977) Inorg Chim Acta 22:169CrossRef
  26.Cyfert M, Latko B, Wawrzeńczyk M (1996) In J Chem Kin 28:108
  27.Dulz G, Sutin N (1963) Inorg Chem 2:917CrossRef
  28.Campion RJ, Purdie N, Sutin N (1964) Inorg Chem 3:1091CrossRef
  29.Diebler H, Sutin N (1964) J Phys Chem 68:174CrossRef
  30.Fedler JH, Fendler EJ (1975) Catalysis in Micellar and Macromolecules Systems. Academic Press, New York
  31.Menger FM, Portnoy CE (1967) J Am Chem Soc 89:4698CrossRef
  32.Al-Awadi N, Wiliams AJ (1999) Org Chem 55:4359CrossRef
  33.Weissberger AI, Lewis ES (1974) Investigation of rates and mechanism of reactions in techniques of chemistry, 4. Wiley, New York, p 421
  
• 作者单位：Hassan A. Ewais (1)
  Abdulla Y. Obaid (1)
  
  1. Chemistry Department, Faculty of Science, King Abdulaziz University, P.O Box 80203, Jeddah, 21589, Saudi Arabia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1572-901X

文摘

The kinetics of oxidation of [FeII(phen)₂(H₂O)₂]2+ (phen = 1,10-phenanthroline) by periodate were investigated in aqueous acidic medium at different [H+] over a temperature range of 20–40 °C. The reaction was studied under pseudo-first-order conditions by taking [IO ₄ − ] > tenfold over [FeII(phen)₂(H₂O) ₂ 2+ ]. The reaction rate increases with increasing [H+], and the kinetics of oxidation obeyed the following rate law:$$ {\text{Rate}} = \left[ {{\text{Fe}}^{\text{II}} ({\text{phen}})_2({\text{H}}_{2} {\text{O}})_{2}^{2 + } } \right]\left[ {{\text{IO}}_{4}^{ - } } \right]\left\{ {k_{4} K_{2} + k_{5} K_{1} K_{3} [{\text{H}}^{ + } ]} \right\} $$The surfactant sodium dodecyl sulfate was found to enhance the rate, whereas cetyltrimethylammonium bromide had little effect. Activation parameters associated with k ₂ and k ₃ were calculated. An electron transfer from Fe(II) to I(VII) is identified as the rate-determining step. The I(VI) species thus generated reacts in a fast step with another Fe(II) complex. Page %P Close Plain text Look Inside Reference tools Export citation EndNote (.ENW) JabRef (.BIB) Mendeley (.BIB) Papers (.RIS) Zotero (.RIS) BibTeX (.BIB) Add to Papers Other actions Register for Journal Updates About This Journal Reprints and Permissions Share Share this content on Facebook Share this content on Twitter Share this content on LinkedIn Related Content Supplementary Material (0) References (33) References1.Sariego R, Farias L, Moya SA (1997) Polyhedron 16:3847CrossRef2.Johann TW, Barton JK (1996) Philos Trans R Soc Lond A 354:299CrossRef3.Chalk SJ, Tyson JF (1994) Anal Chem 66:660CrossRef4.Woodward MP, Youngy WW, Bloodgood RA (1985) J Immunol Method 78:143CrossRef5.Symons MCR (1955) J Chem Soc 2794. doi:10.​1039/​jr9550002794 6.EL-Ziri FR, Sulfab Y (1977) Inorg Chim Acta 25:15CrossRef7.Ewais HA, Ismail IM, Qusti AH, Abdel-Khalek AA (2013) Oxid Commun 36:6018.Ewais HA, Ismail IM (2013) J Chem Sci 125:1151CrossRef9.Abdel-Khalek AA, Ismail IMI, Nagdy MA, Ewais HA (2012) Oxid Commun 35:32710.Ewais HA, Habib MA, Elroby SAK (2010) Trans Met Chem 35:73CrossRef11.Ewais HA, Nagdy MA, Abdel-Khalek AA (2012) Trans Met Chem 37:525CrossRef12.Abdel-Khalek AA, Mohamed AA, Ewais HA (1999) Trans Met Chem 24:233CrossRef13.Ewais HA, Ismail IM, Ahmed SA, Abdel-Khalek AA (2014) Oxid Commun 37:20914.Sklarz B (1967) Organic chemistry of periodates. Q Rev Chem Soc 21:3–28CrossRef15.Kasim AY, Sulfab Y (1981) Inorg Chem 20:506CrossRef16.Kustin K, Lieberman CE (1964) J Phys Chem 68:3869CrossRef17.Sulfab Y (1976) J Inorg Nucl Chem 38:2271CrossRef18.Hussin MA, Sulfab Y (1982) Trans Met Chem 7:181CrossRef19.Pelizzetti E, Pramauro E (1979) Inorg Chem 18:882CrossRef20.Wilkins RG (1991) Kinetics and mechanism of reactions of transition metal complexes, 2nd edn. VCH Publishers Inc, New YorkCrossRef21.Lever ABP (1984) Inorganic electronic spectroscopy. Elsevier, Amsterdam22.Hadinec I, Jensovsky L, Linek A, Synecek V (1960) Naturwiss 47:377CrossRef23.Ray P (1957) Inorg Synth 5:20124.Crouthamel CE, Hayes AM (1951) J Am Chem Soc Jpn 73:82CrossRef25.Kassim AY, Sulfab Y (1977) Inorg Chim Acta 22:169CrossRef26.Cyfert M, Latko B, Wawrzeńczyk M (1996) In J Chem Kin 28:10827.Dulz G, Sutin N (1963) Inorg Chem 2:917CrossRef28.Campion RJ, Purdie N, Sutin N (1964) Inorg Chem 3:1091CrossRef29.Diebler H, Sutin N (1964) J Phys Chem 68:174CrossRef30.Fedler JH, Fendler EJ (1975) Catalysis in Micellar and Macromolecules Systems. Academic Press, New York31.Menger FM, Portnoy CE (1967) J Am Chem Soc 89:4698CrossRef32.Al-Awadi N, Wiliams AJ (1999) Org Chem 55:4359CrossRef33.Weissberger AI, Lewis ES (1974) Investigation of rates and mechanism of reactions in techniques of chemistry, 4. Wiley, New York, p 421 About this Article Title Kinetics and mechanism of the oxidation of diaquabis(1,10-phenanthroline) iron(II) by periodate in aqueous and micellar media Journal Transition Metal Chemistry Volume 41, Issue 3 , pp 357-362 Cover Date2016-04 DOI 10.1007/s11243-016-0032-9 Print ISSN 0340-4285 Online ISSN 1572-901X Publisher Springer International Publishing Additional Links Register for Journal Updates Editorial Board About This Journal Manuscript Submission Topics Catalysis Physical Chemistry Inorganic Chemistry Industry Sectors Materials & Steel Chemical Manufacturing IT & Software Telecommunications Aerospace Oil, Gas & Geosciences Authors Hassan A. Ewais (1) Abdulla Y. Obaid (1) Author Affiliations 1. Chemistry Department, Faculty of Science, King Abdulaziz University, P.O Box 80203, Jeddah, 21589, Saudi Arabia Continue reading... To view the rest of this content please follow the download PDF link above.