Co-hydrotreating of straight-run diesel fraction and vegetable oil on Co(Ni)-PMo/Al2O3 catalysts

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• 作者：P. A. Nikul’shin ; V. A. Sal’nikov ; Al. A. Pimerzin ; Yu. V. Eremina…
• 关键词：co ; hydrotreating ; straight ; run diesel fraction ; hydrodesulfurization ; hydrodeoxygenation ; vegetable oil ; NiMoS ; CoMoS
• 刊名：Petroleum Chemistry
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：56
• 期：1
• 页码：56-61
• 全文大小：1,483 KB
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• 作者单位：P. A. Nikul’shin (1)
  V. A. Sal’nikov (1)
  Al. A. Pimerzin (1)
  Yu. V. Eremina (1)
  A. S. Koklyukhin (1)
  V. S. Tsvetkov (1)
  A. A. Pimerzin (1)
  
  1. Samara State Technical University, Samara, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Industrial Chemistry and Chemical Engineering
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1555-6239

文摘

The process of co-hydrotreatment of straight-run diesel fraction (DF) and vegetable oil (VO) on Co(Ni)-PMo/Al₂O₃ catalysts prepared from H₃PMo₁₂O₄₀ and cobalt (nickel) citrate has been studied. It has been shown that under conditions close to those in the industry, the complete conversion of fatty acid triglycerides (FATG) is achieved on the catalysts of both types to give an ultraclean hydrotreating product in a 97% yield and a cetane number of 5 points above that of the hydrotreating product of the DF alone. The degree of hydrodesulfurization (HDS) is reduced more significantly on the Co-PMo/Al₂O₃ catalyst than in the case of Ni-PMo/Al₂O₃. The catalysts are more susceptible to deactivation in the hydrotreating of the blended feedstock containing VO. The Co-PMo/Al₂O₃ sample is less stable than Ni-PMo/Al₂O₃. Examination of the spent catalysts by transmission electron microscopy has shown that the average particle length of the active phase of Co-PMo/Al₂O₃ increases, whereas this increment for Ni-PMo/Al₂O₃ is insignificant, indicating higher stability of particles of the NiMoS phase. Thus, the co-hydrotreating of petroleum fractions and vegetable oil is more reasonable to carry out on NiMo/Al₂O₃ catalysts. Keywords co-hydrotreating straight-run diesel fraction hydrodesulfurization hydrodeoxygenation vegetable oil NiMoS CoMoS