Peculiarities of magnetic exchange in bi- and tetranuclear copper(II) complexes with organic ligands based on 1,3-diaminopropan-2-ol
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- 作者：V. V. Lukov ; I. N. Shcherbakov…
- 关键词：magnetochemistry ; exchange ; bound complexes ; quantum ; chemical calculations ; exchange parameters ; magnetostructural relationships ; hydrazones ; azomethines ; molecular magnetics
- 刊名：Russian Journal of Coordination Chemistry
- 出版年：2017
- 出版时间：January 2017
- 年：2017
- 卷：43
- 期：1
- 页码：1-20
- 全文大小：
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Physical Chemistry; Inorganic Chemistry;
- 出版者：Pleiades Publishing
- ISSN：1608-3318
- 卷排序：43
文摘
The main types of mechanisms of exchange interactions are considered in the review in the framework of experimental and theoretical analyses. The electronic and geometric factors that exert a determining effect on the magnetic properties of the bi- and tetranuclear complexes of transition metals based on hydrazones and azomethines of 1,3-diaminopropan-2-ol are revealed.