Comparing microcrystalline with spherical nanocrystalline cellulose from waste cotton fabrics

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• 作者：Rui Xiong (1)
  Xinxing Zhang (1) xxzwwh@126.com
  Dong Tian (1)
  Zehang Zhou (1)
  Canhui Lu (1) canhuilu@263.net
• 关键词：Keywords ; Microcrystalline cellulose – ; Spherical nanocrystalline cellulose – ; Waste cotton fabrics – ; Acid hydrolysis – ; Morphology – ; Structure
• 刊名：Cellulose
• 出版年：2012
• 出版时间：August 2012
• 年：2012
• 卷：19
• 期：4
• 页码：1189-1198
• 全文大小：568.6 KB
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• 作者单位：1. State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu, 610065 China
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Bioorganic Chemistry
  Physical Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer Netherlands
• ISSN：1572-882X

文摘

Microcrystalline cellulose (MCC) and spherical nanocrystalline cellulose (SNCC) were successfully prepared from waste cotton fabrics through acid hydrolysis. The comparative analysis of the morphology and structure between the obtained MCC and SNCC was carried out. The SNCC suspension exhibited higher stability than the MCC suspension. Transmission electron microscopy in combination with atomic force microscopy showed that the cellulose nanospheres with average size of 35 nm were achieved, while the average particle size of MCC was 49 μm. The MCC and SNCC had similar functional groups and crystalline structure as confirmed by Fourier transform infrared spectroscopy and X-ray diffraction analysis, respectively. Viscometric average molecular weight measurement and thermo gravimetric analysis indicated that the degree of polymerization and thermal stability of SNCC was lower than that of MCC. These results should improve understanding of the characteristics of MCC and SNCC derived from waste cotton fabrics and lead to many new applications.