Investigation of the catalytic behavior of a Cu coordination polymer capped polyoxometalate as an oxidation catalyst
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- 作者：Faezeh Farzaneh ; Faezeh Moghzi
- 关键词：Hybrid organic–inorganic ; Cu ; coordination polymer ; Polyoxoanions ; Oxidation ; Alkanes ; Alkenes
- 刊名：Reaction Kinetics, Mechanisms and Catalysis
- 出版年：2015
- 出版时间：June 2015
- 年：2015
- 卷：115
- 期：1
- 页码：175-185
- 全文大小：754 KB
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Faezeh Moghzi (1)
1. Department of Chemistry, Alzahra University, Vanak, Tehran, Iran - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Catalysis
Industrial Chemistry and Chemical Engineering
Physical Chemistry - 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
- ISSN：1878-5204
文摘
A multifunctional organic–inorganic hybrid based on a Cu coordination polymer capped polyoxometalate (H3PMo12O40) designated as compound 1 with [CuI(4,4-bipy)]3[PMo 10 VI Mo 2 V O40{CuII(2,2-bipy)}] formula was prepared using CuCl2·2H2O, 4,4-bipy, 2,2-bipy and H3PMo12O4 in water under hydrothemal conditions. The prepared compound 1 was characterized by FTIR, XRD and chemical analysis techniques. It was found that the compound successfully catalyzes the epoxidation of various alkenes such as diphenyl ethylene, trans-stilbene, cyclohexene, norbornene, styrene and cyclooctene and oxidation of alkanes such as fluorene, adamantane, diphenylmethane, cyclohexane and cyclooctane, in acetonitrile with 20-9?% conversion and 53-00?% selectivity with tert-butyl hydroperoxide as oxidant under optimized condition. This heterogeneous catalyst could be easily recovered and reused after reaction without loss of activity.