Multifunctional Cu(II) organic–inorganic hybrid as a catalyst for Knoevenagel condensation

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• 作者：Faezeh Farzaneh ; Mahtab Kashani Maleki…
• 关键词：Cu coordination polymer ; Mo ; polyoxometalate ; Knoevenagel reaction ; Heterogeneous catalyst
• 刊名：Reaction Kinetics, Mechanisms and Catalysis
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：117
• 期：1
• 页码：87-101
• 全文大小：1,143 KB
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• 作者单位：Faezeh Farzaneh (1)
  Mahtab Kashani Maleki (1)
  Mehdi Ghandi (2)
  
  1. Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, Vanak, P.O. Box 1993891176, Tehran, Iran
  2. School of Chemistry, College of Science, University of Tehran, P.O. Box 14155 6455, Tehran, Iran
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Industrial Chemistry and Chemical Engineering
  Physical Chemistry
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1878-5204

文摘

In this study, organic–inorganic hybrid materials based on polyoxometalate and copper coordination polymer, [CuI(4,4′-bipy)]₃[PMo ₁₀ VI Mo ₂ V O₄₀{CuII(2,2′-bipy)}] designated as CuMo-CP(1), were prepared and characterized by various techniques including X-ray powder diffraction (XRD), infrared spectroscopy (FT-IR), and elemental analysis. It was found that the CuMo-CP(1) can be used as an efficient heterogeneous bifunctional acid-base catalyst for Knoevenagel condensation of aromatic aldehydes and cyclohexanone with malononitrile or ethyl cyanoacetate at 60 °C in ethanol. Obtaining the corresponding Knoevenagel adduct in moderate to excellent conversion yields within 4 h is promising. The catalyst can be easily recovered from the reaction mixture and reused for three times without significant loss of activity. Keywords Cu coordination polymer Mo-polyoxometalate Knoevenagel reaction Heterogeneous catalyst