Densities of Fe–Ni melts and thermodynamic correlations

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• 作者：Manabu Watanabe ; Masayoshi Adachi ; Hiroyuki Fukuyama
• 刊名：Journal of Materials Science
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：51
• 期：7
• 页码：3303-3310
• 全文大小：1,421 KB
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• 作者单位：Manabu Watanabe (1)
  Masayoshi Adachi (1)
  Hiroyuki Fukuyama (1)
  
  1. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai, 980-8577, Japan
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Characterization and Evaluation Materials
  Polymer Sciences
  Continuum Mechanics and Mechanics of Materials
  Crystallography
  Mechanics
  
• 出版者：Springer Netherlands
• ISSN：1573-4803

文摘

The densities of liquid Fe–Ni alloys were measured accurately by combination of an electromagnetic levitation technique and a static magnetic field. The static magnetic field suppressed the surface oscillation of the levitated sample droplet, which reduced the experimental uncertainty in the density measurement. Densities were determined over a wide temperature range and included a supercooled region. The densities of all Fe–Ni alloys investigated vary linearly with temperature over the range of measurements. The excess volumes were slightly positive over the entire composition range. The results were discussed within a thermodynamic framework using relationship between excess volume and thermodynamic properties such as excess Gibbs energy and enthalpy of mixing. The excess volume is correlated positively with excess Gibbs energy and enthalpy of mixing for various binary alloy systems.