A self-assembled (H2O)20(CH3OH)4 binary cluster containing a grail-shaped hexadecameric water cluster trapped in the cavity of a m
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- 作者：GengGeng Luo (1)
WeiJun He (1)
Li Liu (1)
ShengHui Wu (1)
DongXu Li (1)
ZiJing Xiao (1)
JingCao Dai (1) - 关键词：water ; methanol binary cluster ; (H2O)16 cluster ; (H2O)20 cluster ; boat structure
- 刊名：SCIENCE CHINA Chemistry
- 出版年：2012
- 出版时间：December 2012
- 年：2012
- 卷：55
- 期：12
- 页码：2507-2514
- 全文大小：955KB
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WeiJun He (1)
Li Liu (1)
ShengHui Wu (1)
DongXu Li (1)
ZiJing Xiao (1)
JingCao Dai (1)
1. Institute of Materials Physical Chemistry, College of Materials Science & Engineering, Huaqiao University, Xiamen, 361021, China - ISSN：1869-1870
文摘
A discrete centrosymmetric (H2O)20(CH3OH)4 binary cluster was confined in the cavity of a metal-ligand hybrid [Ag4(bpda)2(bpp)4·14H2O·2CH3OH] n (1) (where bpp = 1,3-bis(4-pyridyl)propane and H2bpda = 2,2-biphenyldicarboxylic acid). The novel mixed water-methanol cluster consists of one grail-shaped hexadecameric cluster, four dangling water and four hanging methanol molecules. The (H2O)16 cluster is composed of two pairs of edge-sharing (H2O)5 rings attached to one (H2O)4 core with twenty hydrogen bonds. Alternatively, the (H2O)16 cluster is structurally similar to a complicated hydrocarbon generated by undergoing [2+2] cycloaddition of 1,2,3,4,5,6-hexahydropentalene, which reveals the resemblance between water clusters and organic compounds.