A Comparative Study of Micellization Behavior of an Ethoxylated Alkylphenol in Aqueous Solutions of Glycine and Leucine

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• 作者：Suvarcha Chauhan (1)
  Kundan Sharma (1)
  Kuldeep Kumar (1)
  Girish Kumar (2)
  
• 关键词：Glycine ; Leucine ; Ethoxylated alkylphenol ; Isentropic compressibility (κ s ) ; Apparent molar volume (? v ) ; Apparent molar adiabatic compression (? κ )
• 刊名：Journal of Surfactants and Detergents
• 出版年：2014
• 出版时间：January 2014
• 年：2014
• 卷：17
• 期：1
• 页码：161-168
• 全文大小：304 KB
• 作者单位：Suvarcha Chauhan (1)
  Kundan Sharma (1)
  Kuldeep Kumar (1)
  Girish Kumar (2)
  
  1. Department of Chemistry, H. P. University, Shimla, 171005, India
  2. JCDAV College, Dasuya, 144205, India
  
• ISSN：1558-9293

文摘

Densities (d) and sound velocities (v) of an ethoxylated alkyl phenol surfactant in aqueous solutions of two amino acids, namely glycine and leucine, have been measured over a temperature range of 25-0?°C at intervals of 5?°C by using density and sound analyzers. Experimental data have been used to calculate the isentropic compressibilities (κ s ), apparent molar volumes (? v ) and apparent molar adiabatic compressions (? κ ) in order to explain amino acid–surfactant interactions. The results have been discussed in terms of the effect of amino acids on the micellization behavior of the surfactant. A comparative study of both the amino acids has been carried out and is found that both amino acids produce a decrease in the CMC value of nonionic surfactant but to different extents.