Copper(II)–8-mercaptoquinoline, copper(II)–5,8-dimercaptoquinoline and copper(II)–5-thiomethyl-8-mercaptoquinoline complexing in a copper(II)hexacyanoferrate(II) gelatin-immobilized

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• 作者：Mikhailov ; Oleg V. ; Tatarintseva ; Tatyana B. ; Gorbunova ; Tatyana S. ; Sopin ; Vladimir F.
• 刊名：Transition Metal Chemistry
• 出版年：2000
• 出版时间：2000
• 年：2000
• 卷：25
• 期：1
• 页码：45-51
• 全文大小：160 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1572-901X

文摘

Novel complexing processes in the Cu$^II$–8-mercaptoquinoline, Cu$^II$–5,8-dimercaptoquinoline and Cu$^II$–5-thiomethyl-8-mercaptoquinoline systems proceeding in the copper(II)hexacyanoferrate(II) gelatin-immobilized matrix in contact with aqueous solutions of the ligands indicated, have been studied. Under the conditions specified for complexing in the Cu$^II$–8-mercaptoquinoline system, only a monomeric water-insoluble coordination compound was formed. In the Cu$^II$–5,8-dimercaptoquinoline system, three coordination compounds were formed and, in the Cu$^II$–5-thiomethyl-8-mercaptoquinoline system, two such compounds were formed. Conversely, complexing in solution or solid phase results in the formation only coordination compounds in each of the system studied.