An isomer of a POM-based hybrid compound formed through different linkage between CuI ions and pyrazine

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• 作者：Yang Yang ; Chunhe Li ; Ya-Guang Chen
• 关键词：Polyoxometalate ; 3D hybrid compounds ; Double ; layer structure ; Copper ; Pyrazine
• 刊名：Journal of Inclusion Phenomena and Macrocyclic Chemistry
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：84
• 期：3-4
• 页码：203-208
• 全文大小：1,517 KB
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• 作者单位：Yang Yang (1)
  Chunhe Li (2)
  Ya-Guang Chen (1)
  
  1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, 5268 Renmin Street, Changchun, 130024, People’s Republic of China
  2. Department of Mathematics, University of California, Irvine, CA, 92617, USA
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Organic Chemistry
  Food Science
  Crystallography
  
• 出版者：Springer Netherlands
• ISSN：1573-1111

文摘

One 3D Keggin polyoxometalates-based hybrid compound, [Cu₄(pz)₆(H₂O)₂(SiW₁₂O₄₀)] (1) (pz = pyrazine), was hydrothermally synthesized and characterized by an elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction. In compound 1, [Cu₄(pz)₆(H₂O)₂] _n 4n+ polymeric cation has 2D network structure including ten-metal rings. The two 2D networks are linked through sharing a coordination water into a double-layer structure. [SiW₁₂O₄₀]4− anions are embedded between two double-layers through the coordination of O_t atoms to Cu atoms. The pyrazine molecule is in situ formed from the decarboxylation of pyrazine-2,3-dicarboxylic acid. The IR data of 1 also proved the correctness of the structure due to no characteristic peak of carbonyl group in IR spectrum. Thermogravimetric analysis and fluorescence of 1 are also analyzed and discussed.