Synthesis, crystal, and biological activity of a novel carbene silver(I) complex with imidazole derivative

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• 作者：Lu Jiu-Fu ; Ge Hong-Guang ; Shi Juan
• 刊名：Crystallography Reports
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：60
• 期：7
• 页码：1089-1092
• 全文大小：509 KB
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• 作者单位：Lu Jiu-Fu (1)
  Ge Hong-Guang (1)
  Shi Juan (1)
  
  1. Shaanxi University of Technology, Chemical Engineering College, Hanzhong, 723001, China
  
• 刊物类别：Physics and Astronomy
• 刊物主题：Physics
  Crystallography
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1562-689X

文摘

Reaction of 2-(1-methyl-1,2-dihydroimidazol-3-yl)acetonitrile tetrafluoroborate with silver oxide in dichloromethane readily yields [Ag(DIM)₂]BF₄, where DIM is 2-(1-methyl-1, 2-dihydroimidazol-3-yl)acetonitrile, representing a carbene organic ligand. The title compound was characterized by elemental analysis, IR, MS and single crystal X-ray diffraction. The crystal is of monoclinic system, space group C2/c with a = 14.010(18), b = 8.303(11), c = 14.936(20) ?, β = 93.910(4)°, V = 1639(4) ?3, Z = 4, D _x = 1.771 g/cm3, F (000) = 864, μ(MoK _α) = 1.278 mm-. The final R 1 = 0.0711 and wR 2 = 0.1903 for reflections with I > 2σ(I). In addition, the preliminary biological test showed that the title compound had anti-fungus yeast activity. The article is published in the original.