Pilot-scale treatment of pharmaceutical berberine wastewater by Fenton oxidation
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- 作者：Xiaoyu Cui ; Ping Zeng ; Guanglei Qiu ; Yongqiang Liu…
- 关键词：Fenton ; Berberine wastewater ; Response surface methodology (RSM) ; Optimization
- 刊名：Environmental Earth Sciences
- 出版年：2015
- 出版时间：May 2015
- 年：2015
- 卷：73
- 期：9
- 页码：4967-4977
- 全文大小：2,797 KB
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Ma J, Han BJ, Zhang T, Ch - 作者单位：Xiaoyu Cui (1) (2)
Ping Zeng (1) (2) (3)
Guanglei Qiu (4)
Yongqiang Liu (5)
Yonghui Song (1) (2)
Xiaolin Xie (1) (2)
Lu Han (1) (2)
1. State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China
2. Department of Urban Water Environmental Research, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China
3. State Environmental Protection Key Laboratory of Microorganism Application and Risk Control (MARC), Tsinghua University, Beijing, 100084, China
4. Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore, 119077, Singapore
5. Faculty of Engineering and the Environment, University of Southampton, Southampton, SO17 1BJ, UK - 刊物类别：Earth and Environmental Science
- 刊物主题：None Assigned
- 出版者：Springer Berlin Heidelberg
- ISSN：1866-6299
文摘
Fenton oxidation was used to treat the berberine finished mother liquor wastewater in pilot scale. To evaluate berberine and COD removal efficiency, the main factors, including pH, H2O2 dosage, Fe2+/H2O2 mass ratio and the water flow (Q), were optimized using response surface methodology (RSM). The results showed that under the optimal conditions, pH 3, H2O2/COD molar ratio of 1.25, Fe2+/H2O2 molar ratio of 0.1, Q 100?L/h [with hydraulic retention time (HRT) of 2.5?h], the COD and berberine removal efficiencies were 35.6 and 91.4?% at initial COD concentration of 4061?mg/L and berberine concentration of 709?mg/L, respectively. The (BOD5)/(COD) ratio (B/C) of the wastewater increased from 0 to 0.3, indicating significantly improved biodegradability of wastewater.