Preparation of ZnO–B2O3–SiO2:Mn2+ optical-storage glass–ceramics with different ZnF2 dopant b
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- 作者：Yi Shen ; Luyao Hou ; Guifu Zuo ; Fengfeng Li…
- 关键词：Sol–gel method ; Luminescence ; Optical ; storage ; Glass–ceramics ; ZnF2
- 刊名：Journal of Sol-Gel Science and Technology
- 出版年：2015
- 出版时间：January 2015
- 年：2015
- 卷：73
- 期：1
- 页码：192-198
- 全文大小：1,284 KB
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- 刊物主题：Chemistry
Ceramics,Glass,Composites,Natural Materials
Inorganic Chemistry
Optical and Electronic Materials
Nanotechnology - 出版者：Springer Netherlands
- ISSN：1573-4846
文摘
ZnO–B2O3-a href='/search?dc.title=SiO&facet-content-type=ReferenceWorkEntry&sortOrder=relevance' class='reference-link webtrekk-track' gaCategory="Internal link" gaLabel="SiO" gaAction="reference keyword">SiO2:Mn2+ (ZBSM) optical-storage glass–ceramics doped with ZnF2 were successfully prepared via sol–gel method. The effects of ZnF2 additive on the preparation of glass–ceramics were analyzed by differential scanning calorimetry. X-ray diffraction analysis, scanning electron microscopy and energy dispersive spectroscopy were employed to investigate the mineralogical and micro-structural characteristics of ZBSM (ZnF2) optical-storage glass–ceramics. Optical storage properties of the samples were measured through photoluminescence, long-lasting phosphor (LLP) decay curves and thermo-luminescence (TL). LLP decay curves demonstrated that lower phonons energy of F?/sup> could generate more stable metastable energy. TL spectra illustrated that the sample with 20?mol% ZnF2 content showed the best performance.