Electrophoretic deposition of nano-sized BaTiO3
详细信息 查看全文
- 作者：Aydin Dogan ; Goktug Gunkaya ; Ender Suvaci and Markus Niederberger
- 刊名：Journal of Materials Science
- 出版年：2006
- 出版时间：December, 2006
- 年：2006
- 卷：41
- 期：24
- 页码：8196-8201
- 全文大小：385 KB
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Materials Science
Characterization and Evaluation Materials
Polymer Sciences
Continuum Mechanics and Mechanics of Materials
Crystallography
Mechanics - 出版者：Springer Netherlands
- ISSN：1573-4803
文摘
In this study, a non-aqueous method in a simple one pot reaction process was employed to synthesize nano-sized BaTiO3 particles and then electrophoretic deposition technique was employed for thin film coatings. In the first step of the preparation, metallic barium is directly dissolved in benzyl alcohol at slightly elevated temperatures. Then titanium isopropoxide was added following by a solvothermal treatment. At the end of the reaction, nearly spherical BaTiO3 nanoparticles were obtained typically 5 nm in diameter. After establishing the stability of the BaTiO3 suspension in ethanol, electrophoretic deposition process was performed without any additional operation. Alumina with platinum plating was used as substrate. To achieve the optimal process parameters, various voltages were applied by altering the cathode to anode distance as well as deposition time. High voltages application was possible without causing hydrolysis, because of the non-aqueous ethanol medium with higher surface charge of the nanoparticles. The deposited surface coatings were dried in air and sintered at various temperatures. SEM, EDX and XRD analysis were employed for the investigation of the coating.