Study of the surface reaction mechanism of Li4Ti5O12 anode for lithium-ion cells
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- 作者：Jingjing Gao ; Benli Gong ; Qingtang Zhang ; Guodong Wang ; Yangjie Dai ; Weifeng Fan
- 关键词：Solid ; electrolyte interface ; Li4Ti5O12 ; Gas generation ; Lithium ; ion battery ; Additive
- 刊名：Ionics
- 出版年：2015
- 出版时间：September 2015
- 年：2015
- 卷：21
- 期：9
- 页码：2409-2416
- 全文大小：1,488 KB
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Benli Gong (3)
Qingtang Zhang (4)
Guodong Wang (1)
Yangjie Dai (1)
Weifeng Fan (1)
1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041, People’s Republic of China
2. Graduate University of Chinese Academy of Sciences, Beijing, 100039, People’s Republic of China
3. Sichuan Xingneng New Materials Co., LTD, Guangyuan, 628317, People’s Republic of China
4. School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou, 730050, People’s Republic of China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Electrochemistry
Materials Science
Physical Chemistry
Condensed Matter
Renewable Energy Sources
Electrical Power Generation and Transmission - 出版者：Springer Berlin / Heidelberg
- ISSN：1862-0760
文摘
The formation of solid-electrolyte interface (SEI) film on the surface of LTO electrode at 25 and 55 °C has been investigated. It is found that the SEI film, which is mainly composed of Li2CO3, LiF, and ROCO2Li, can be formed on the surface of LTO electrode. The differences of SEI film under 25 and 55 °C are further discussed. The results reveal that the temperature has an effect on the morphology of formed SEI film. With the temperature increasing, the decomposition of carbonate species makes the SEI film became thicker and uneven, and also produces C2H4, which is attributed to the swelling of LTO cells at 55 °C. When adding 0.5 wt.% succinonitrile (SN, CN–[CH2]2–CN) in the electrolyte, the gassing behavior of the LTO cells at 3 C rate at 55 °C can be obviously suppressed and the cyclic performance of the cells also improved. Keywords Solid-electrolyte interface Li4Ti5O12 Gas generation Lithium-ion battery Additive