Study on Fe3O4/polyaniline electromagnetic composite hollow spheres prepared against sulfonated polystyrene colloid template
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- 作者：Huifang Xu (1)
Haijiao Zhang (2)
Tong Lv (1)
Huawei Wei (1)
Fei Song (1) - 关键词：Hollow spheres ; Template ; Electromagnetic ; Polyaniline ; Fe3O4
- 刊名：Colloid & Polymer Science
- 出版年：2013
- 出版时间：July 2013
- 年：2013
- 卷：291
- 期：7
- 页码：1713-1720
- 全文大小：836KB
- 参考文献：1. Caruso F, Caruso RA, M?hwald H (1998) Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating. Science 282:1111-114 CrossRef
2. Wang D, Zeng H (2009) Multifunctional roles of TiO2 nanoparticles for architecture of complex core–shells and hollow spheres of SiO2–TiO2–polyaniline system. Chem Mater 21:4811-823 CrossRef
3. Hu J, Chen M, Fang X, Wu L (2011) Fabrication and application of inorganic hollow spheres. Chem Soc Rev 40:5472-491 CrossRef
4. Ding SJ, Zhang CL, Yang M, Qu XZ, Lu YF, Yang ZZ (2006) Template synthesis of composite hollow spheres using sulfonated polystyrene hollow spheres. Polymer 47:8360-366 CrossRef
5. Han SH, Hou WG, Xu J, Li ZM (2004) Synthesis of hollow spherical silica with MCM-41 mesoporous structure. Colloid Polym Sci 282:1286-291 CrossRef
6. Saini P, Choudhary V, Vijayan N, Kotnala RK (2012) Improved electromagnetic interference shielding response of poly(aniline)-coated fabrics containing dielectric and magnetic nanoparticles. J Phys Chem C 116:13403-3412 CrossRef
7. Zhang YJ, Lin YW, Chang CC, Wu TM (2010) Magnetic properties of hydrophilic iron oxide/polyaniline nanocomposites synthesized by in situ chemical oxidative polymerization. Synth Met 160:1086-091 CrossRef
8. He ZF, Fang Y, Wang XJ, Pang H (2011) Microwave absorption properties of PANI/CIP/Fe3O4 composites. Synth Met 161:420-25 CrossRef
9. Gu HB, Huang YD, Zhang X, Wang Q, Zhu JH, Shao L, Haldolaarachchige H, Young DP, Wei SY, Guo ZH (2012) Magnetoresistive polyaniline–magnetite nanocomposites with negative dielectrical properties. Polymer 53:801-09 CrossRef
10. Saini P, Choudhary V, Singh BP, Mathur RB, Dhawan SK (2009) Polyaniline–MWCNT nanocomposites for microwave absorption and EMI shielding. Mat Chem Phys 13:919-26 CrossRef
11. Saini P, Arora M Microwave absorption and EMI shielding behavior of nanocomposites based on intrinsically conducting polymers, graphene and carbon nanotubes. In: Gomes AD (ed) New polymers for special applications. InTech, Croatia. doi:10.5772/48779
12. Chung DDL (2001) Electromagnetic interference shielding effectiveness of carbon materials. Carbon 39:279-85 CrossRef
13. Yang YL, Gupta MC (2005) Novel carbon nanotube–polystyrene foam composites for electromagnetic interference shielding. Nano Lett 5:2131-134 CrossRef
14. Li N, Huang Y, Du F, He XB, Lin X, Gao HJ, Ma YF, Li FF, Chen YS, Eklund PC (2006) Electromagnetic interference (EMI) shielding of single-walled carbon nanotubes epoxy composites. Nano Lett 6:1141-145 CrossRef
15. Wang J, Xu HF, Song JW, Zhang HJ, Gao BL, Huang YD (2011) Lightweight glass/Fe3O4–polyaniline composite hollow spheres with conductive and magnetic properties. J Mater Sci 46:2955-962 CrossRef
16. Yang CM, Li HY, Xiong DB, Cao ZY (2009) Hollow polyaniline/Fe3O4 microsphere composites: preparation, characterization, and applications in microwave absorption. React Funct Polym 69:137-44 CrossRef
17. Nakashima T, Kimizuka N (2003) Interfacial synthesis of hollow TiO2 microspheres in ionic liquids. J Am Chem Soc 125:6386-387 CrossRef
18. Jiang YQ, Yang SF, Ding XF, Guo YP, Bala H, Zhao JZ, Yu KF, Wang ZC (2005) Synthesis and catalytic activity of stable hollow ZrO2–SiO2 spheres with mesopores in the shell wall. J Mater Chem 15:2041-046 CrossRef
19. Discher DE, Eisenberg A (2002) Polymer vesicles. Science 297:967-73 CrossRef
20. Tartaj P, Gonz?lez-Carre?o SCJ (2001) Single-step nanoengineering of silica coated maghemite hollow spheres with tunable magnetic properties. Adv Mater 13:1620-624 CrossRef
21. Yin YD, Rioux RM, Erdonmez CK, Hughes S, Somorjai GA, Alivisatos AP (2004) Formation of hollow nanocrystals through the nanoscale Kirkendall effect. Science 304:711-14 CrossRef
22. Ding SJ, Wei W, Yang ZZ (2009) Composite colloids and patterning. Polymer 50:1609-615 CrossRef
23. Yang M, Ma J, Niu ZW, Dong X, Xu HF, Meng ZK, Jin ZG, Lu YF, Hu ZB, Yang ZZ (2005) Synthesis of spheres with complex structures using hollow latex cages as templates. Adv Funct Mater 15:1523-528 CrossRef
24. Arnal PM, Schüth F, Kleitz F (2006) A versatile method for the production of monodisperse spherical particles and hollow particles: templating from binary core–shell structures. Chem Comm 11:1203-205
25. Wang YJ, Angelatos AS, Caruso F (2008) Template synthesis of nanostructured materials via layer-by-layer assembly. Chem Mater 20:848-58 CrossRef
26. Zhang CL, Ding SJ, Li JJ, Xu HF, Sun LL, Wei W, Li CP, Liu JG, Qu XZ, Lu YF, Yang ZZ (2008) Interpenetration network (IPN) assisted transcription of polymeric hollow spheres: a general approach towards composite hollow spheres. Polymer 49:3098-102 CrossRef
27. Yang ZZ, Niu ZW, Lu YF, Hu ZB, Han CC (2003) Templated synthesis of inorganic hollow spheres with tunable cavity size onto core/shell gel particles. Angew Chem Int Ed 42:1943-945 CrossRef
28. Yang M, Ma J, Zhang CL, Lu YF, Yang ZZ (2005) General synthetic route toward functional hollow spheres with double-shelled structures. Angew Chem Int Ed 44:6727-730 CrossRef
29. Xu HF, Wei W, Zhang CL, Ding SJ, Qu XZ, Liu JG, Lu YF, Yang ZZ (2007) Low-temperature facile template synthesis of crystalline inorganic composite hollow spheres. Chem Asian J 2:828-36 CrossRef
30. Xu HF, Ding SJ, Wei W, Zhang CL, Qu XZ, Liu JG, Yang ZZ (2007) Template synthesis of tin-doped indium oxide (ITO)/polymer and the corresponding carbon composite hollow colloids. Colloid Polym Sci 285:1101-107 CrossRef
31. Wang XC, Tang SD, Liu J, He ZQ, An LJ, Zhang CX, Hao JM, Feng W (2009) Uniform Fe3O4–PANi/PS composite spheres with conductive and magnetic properties and their hollow spheres. J Nanopart Res 11:923-29 CrossRef
32. Wang XC, Liu J, Feng XF, Guo MJ, Sun DL (2008) Fabrication of hollow Fe3O4–polyaniline spheres with sulfonated polystyrene templates. Mat Chem Phys 112:319-21 CrossRef
33. Chen L, Xu Z, Dai H, Zhang S (2010) Facile synthesis and magnetic properties of monodisperse Fe3O4/silica nanocomposite microspheres with embedded structures via a direct solution-based route. J Alloy Compd 497:221-27 CrossRef
34. Regazzoni AE, Urrutia GA, Blesa MA, Maroto AJG (1981) Some observations on the composition and morphology of synthetic magnetites obtained by different routes. J Inorg Nucl Chem 43:1489-493 CrossRef
35. Lei ZB, Zhao MY, Dang LQ, An LZ, Lu M, Lo An-Ya YNY, Liu SB (2009) Structural evolution and electrocatalytic application of nitrogen-doped carbon shells synthesized by pyrolysis of near-monodisperse polyaniline nanospheres. J Mater Chem 19:5985-995 CrossRef
36. Pouget JP, Józefowicz ME, Epstein AJ, Tang X, MacDiarmid AG (1991) X-ray structure of polyaniline. Macromolecules 24:779-89 CrossRef - 作者单位：Huifang Xu (1)
Haijiao Zhang (2)
Tong Lv (1)
Huawei Wei (1)
Fei Song (1)
1. School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, 150001, China
2. Modern Manufacture Engineering Center, Heilongjiang Institute of Science and Technology, Harbin, 150027, China - ISSN：1435-1536
文摘
Fe3O4/polyaniline (PANI) composite hollow spheres were prepared by using sulfonated polystyrene (SPS) microspheres as templates. The sulfonic acid groups were applied to induce absorbing Fe3O4 nanoparticle, and subsequently, conductive PANI was grown. Finally, the polystyrene cores were selectively dissolved to yield composite hollow microspheres with electromagnetic properties. The analysis results indicated that the adsorption of Fe3O4 on template core by electrostatic interaction resulted in magnetic composite microspheres. The conductivity of composite hollow spheres was remarkably increased after polyvinylpyrrolidone modification which favored the growth of PANI on SPS/Fe3O4 and enhanced the integrity of hollow microspheres. The saturated magnetization of the composite hollow microspheres was tuned from 2.7 to 9.1?emu/g, and the conductivity was in the range from 10? to 100?S/cm.