Biogenic volatile compound emissions from a temperate forest, China: model simulation

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• 作者：Jianhui Bai ; Tiffany Duhl ; Nan Hao
• 关键词：Biogenic volatile organic compounds ; Isoprene ; Monoterpene ; Emission flux ; Photosynthetically active radiation ; GOME ; 2
• 刊名：Journal of Atmospheric Chemistry
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：73
• 期：1
• 页码：29-59
• 全文大小：2,118 KB
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• 作者单位：Jianhui Bai (1)
  Tiffany Duhl (2)
  Nan Hao (3)
  
  1. LAGEO, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China
  2. National Center for Atmospheric Research, Boulder, CO, 80307, USA
  3. Remote Sensing Technology Institute, Deutsches Zentrum fuer Luft- und Raumfahrt e.V. (DLR), Oberpfaffenhofen, 82234, Wessling, Germany
  
• 刊物类别：Earth and Environmental Science
• 刊物主题：Earth sciences
  Meteorology and Climatology
  Atmospheric Protection, Air Quality Control and Air Pollution
  
• 出版者：Springer Netherlands
• ISSN：1573-0662

文摘

Emissions of biogenic volatile organic compounds (BVOC) were measured using a relaxed eddy accumulation (REA) technique on an above-canopy tower in a temperate forest (Changbai Mountain, Jilin province, China) during the 2010 and 2011 summer seasons. Solar global radiation and photosynthetically active radiation (PAR) were also measured. Based on PAR energy dynamic balance, an empirical BVOC emission and PAR transfer model was developed that includes the processes of BVOC emissions and PAR transfer above the canopy level, including PAR absorption and consumption, and scattering by gases, liquids, and particles (GLPs). Simulated emissions of isoprene and monoterpenes were in agreement with observations. The averages of the relative estimator biases for the flux were 39.3 % for isoprene, and 27.1 % for monoterpenes in the 2010 and 2011 growing seasons, with NMSE (normalized mean square error) values of 0.133 and 0.101, respectively. The observed and simulated mean diurnal variations of isoprene and monoterpenes in the 2010 and 2011 growing seasons were evaluated for the validation of the empirical model. Under observed atmospheric conditions, the sensitivity analysis showed that emissions of isoprene and monoterpenes were more sensitive to changes in PAR than to water vapor content or to the magnitude of the scattering factor. The emissions of isoprene and monoterpenes in the 2010 and 2011 growing seasons (from June to September) were estimated using this empirical model along with hourly observational data, with mean hourly emissions of 1.71 and 1.55 mg m−2 h−1 for isoprene, and 0.48 and 0.47 mg m−2 h−1 for monoterpenes in 2010 and 2011, respectively. As formaldehyde (HCHO) is considered as the main oxidation product of isoprene and monoterpenes, it is necessary to investigate the link between HCHO and BVOC emissions. GOME-2 HCHO vertical column densities (VCDs) can be used to estimate BVOC emission fluxes in the Changbai Mountain temperate forest.