Regioselective mononitration of biphenyl by use of stoichiometric quantities of nitrogen dioxide and molecular oxygen over rare earth cation-exchanged β-zeolite catalysts
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- 作者：Yan Fang Tai ; Xiong Zi Dong ; Hao Shu Xu ; Chun Jie Shi…
- 关键词：Biphenyl ; Nitrogen dioxide ; Mononitration ; Rare earth cations ; β ; Zeolite ; Regioselectivity
- 刊名：Research on Chemical Intermediates
- 出版年：2015
- 出版时间：December 2015
- 年：2015
- 卷：41
- 期：12
- 页码：9643-9653
- 全文大小：811 KB
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25.G. Socrates, Infrared Characteristic Group Frequencies (Wiley, New York, 1980) - 作者单位：Yan Fang Tai (1) (2)
Xiong Zi Dong (1)
Hao Shu Xu (1)
Chun Jie Shi (2)
Xin Hua Peng (1)
1. School of Chemical Engineering, Hefei University of Technology, Hefei, 230009, People’s Republic of China
2. School of Applied Chemistry and Environmental Engineering, Bengbu College, Bengbu, 233000, People’s Republic of China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Catalysis
Physical Chemistry
Inorganic Chemistry - 出版者：Springer Netherlands
- ISSN：1568-5675
文摘
In the presence of molecular oxygen and zeolite La-β with Si/Al2 = 260, regioselective mononitration of biphenyl with stoichiometric quantities of liquid nitrogen dioxide occurs at 20 °C to yield mononitrobiphenyl, as the main product, in yields up to 82.7 %. The 2-nitrobiphenyl:4-nitrobiphenyl isomer ratio is 0.34. The process is eco-friendly and inexpensive, and the zeolite is easily regenerated by simple work-up to give results similar to those obtained with the fresh catalyst. Keywords Biphenyl Nitrogen dioxide Mononitration Rare earth cations β-Zeolite Regioselectivity