Studies on gas-phase cyclometalations of [ArNi(PPh3)n]+ (n = 1 or 2) by electrospray ionization tandem mass spectrometry
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- 作者：Jing Zhou (1)
Qian Zhao (2)
Wen-Wen Chen (2)
Haoyang Wang (1)
Guo-Qiang Lin (2)
Ming-Hua Xu (2)
Yinlong Guo (1) - 刊名：Journal of The American Society for Mass Spectrometry
- 出版年：2010
- 出版时间：July 2010
- 年：2010
- 卷：21
- 期：7
- 页码：1265-1274
- 全文大小：814KB
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67. Hong, R. PhD thesis, Shanghai Inst. of Org. Chem. Chinese. Acad. Sci. 2001, 43鈥?4. - 作者单位：Jing Zhou (1)
Qian Zhao (2)
Wen-Wen Chen (2)
Haoyang Wang (1)
Guo-Qiang Lin (2)
Ming-Hua Xu (2)
Yinlong Guo (1)
1. Shanghai Mass Spectrometry Center, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 200032, Shanghai, China
2. CAS Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 200032, Shanghai, China
文摘
Gas-phase cyclometalation of [ArNi(PPh3)n]+ (n = 1, 2) complexes have been studied by ESI-MS/MS. The electron-donating substituents of aromatic iodides in the para position were found to inhibit the cyclometalation process of losing ArH, while the electron-withdrawing substituents in the para position were found to enhance it. These results indicate that the cyclometalation process of losing ArH is favored by electron-deficient aromatic groups. In addition, the detailed dissociation pathways of the cationic nickel complexes were studied, and among these pathways, the process of aryl-aryl interchange was also found to proceed in ESI-MS/MS.