Natural and anthropogenic influences on the arsenic geochemistry of lacustrine sediment from a typical fault-controlled highland lake: Yangzonghai Lake, Yunnan, China
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  • 作者:Xu-Heng Zhu ; Ping-Ping Zhang ; Xue-Gang Chen ; Dai-Dai Wu…
  • 关键词:Arsenic ; Groundwater ; Anthropogenic influence ; Highland lake ; Correlation coefficient
  • 刊名:Environmental Earth Sciences
  • 出版年:2016
  • 出版时间:February 2016
  • 年:2016
  • 卷:75
  • 期:3
  • 全文大小:2,007 KB
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  • 作者单位:Xu-Heng Zhu (1)
    Ping-Ping Zhang (1) (2)
    Xue-Gang Chen (1) (2)
    Dai-Dai Wu (3)
    Ying Ye (1)

    1. Ocean College, Zhejiang University, Hangzhou, 310058, Zhejiang, People’s Republic of China
    2. State Key Laboratory of Satellite Ocean Environment Dynamics, Second Institute of Oceanography, State Oceanic Administration, Hangzhou, 310012, Zhejiang, People’s Republic of China
    3. Guangzhou Institute of Energy, China Academy of Science, Guangzhou, 510640, Guangdong, People’s Republic of China
  • 刊物类别:Earth and Environmental Science
  • 刊物主题:None Assigned
  • 出版者:Springer Berlin Heidelberg
  • ISSN:1866-6299
文摘
Located in Yunnan province, China, Yangzonghai Lake is a fault-controlled highland lake where arsenic concentration suddenly increased 20-fold in 2008, which raised great environmental concerns. It is therefore a nice prototype to study the natural and/or anthropogenic influences on the arsenic geochemistry of the sediment in highland lakes. In this study, lacustrine sediments were recovered from the lake and the differences in the occurrence of arsenic between the surface (0–10 cm depth) and sub-surface sediments (>20 cm) were investigated. The arsenic distribution in the sub-surface sediment was in accordance with the locations of springs, suggesting that arsenic therein was affected by groundwater. The surface sediment, however, was affected by human contamination carried by Yangzong River. In the sub-surface sediment, arsenic concentrations increased with pH values but decreased with redox potentials. Higher grain sizes corresponded to lower arsenic contents. Arsenic was strongly positively correlated with Sb and Bi due to their similar geochemical behaviors. In the surface sediment, however, the human activities increased the arsenic concentration in the sediment and weakened the correlations between arsenic occurrence, pH/Eh values, grain size, and trace metals. Although the average differences in the trace element concentrations between surface and sub-surface sediments over the entire Yangzonghai Lake were less than 15 %, the pairwise differences were statistically significant, and the southern portion of the lake showed the greatest anthropogenic influence. This research will provide important information on the geochemistry and environmental science of arsenic in fault-controlled highland lakes.

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