Thermoacoustic, volumetric, and viscometric investigations in the binary mixtures of 1,4-dioxane with n-hexane or n-heptane or n-octane

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• 作者：Sk. Md Nayeem ; M. Kondaiah ; K. Sreekanth…
• 关键词：Binary mixtures of 1 ; 4 ; dioxane + n ; hexane/n ; heptane/n ; octane ; Ultrasonic velocity ; Viscosity ; Redlich–Kister polynomial ; Molecular interactions
• 刊名：Journal of Thermal Analysis and Calorimetry
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：123
• 期：3
• 页码：2241-2255
• 全文大小：2,161 KB
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• 作者单位：Sk. Md Nayeem (1)
  M. Kondaiah (2)
  K. Sreekanth (3)
  M. Srinivasa Reddy (4)
  D. Krishna Rao (5)
  
  1. Department of Physics, KRK Government Degree College, Addanki, 523201, A.P., India
  2. Department of Physics, NM Government Degree College, Jogipet, 502270, Telangana, India
  3. Department of Physics, PBN College, Nidubrolu, 522124, A.P., India
  4. Department of Chemistry, KRK Government Degree College, Addanki, 523201, A.P., India
  5. Department of Physics, Acharya Nagarjuna University, Nagarjunanagar, 522510, A.P., India
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Sciences
  Polymer Sciences
  Physical Chemistry
  Inorganic Chemistry
  Measurement Science and Instrumentation
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1572-8943

文摘

Ultrasonic velocity, u, density, \( \rho \), and viscosity, \( \eta \), have been measured in the binary liquid mixture of 1,4-dioxane with n-hexane or n-heptane or n-octane at 308.15, 313.15, and 318.15 K over the entire composition range. Properties such as molar volume, V _m, intermolecular free length, L _f, acoustic impedance, Z, internal pressure, π _i, enthalpy, ΔH, Gibb’s free energy of activation of viscous flow, \( \Delta G^{*} \), and their excess/deviation properties such as deviations in ultrasonic speed, ∆u, viscosity, \( \Delta \eta \), excess molar volume, \( V_{\text{m}}^{\text{E}} \), excess intermolecular free length, \( L_{\text{f}}^{\text{E}} \), excess acoustic impedance, Z E, excess internal pressure, \( \pi_{\text{i}}^{\text{E}} \), excess enthalpy, \( \Delta H^{\text{E}} \), and excess Gibb’s free energy of activation of viscous flow, \( \Delta G^{{*{\text{E}}}} \), have been calculated from the experimental data. The calculated deviation/excess properties have been fitted to the Redlich–Kister-type polynomial equation. Partial molar volumes, (\( \bar{V}_{\text{m,1}} \), \( \bar{V}_{\text{m,2}} \)), and excess partial molar volumes, (\( \bar{V}_{\text{m,1}}^{\text{E}} \), \( \bar{V}_{\text{m,2}}^{\text{E}} \)), have also been evaluated. The observed positive and negative values of the relevant deviation/excess properties are attributed to the dominance of weak interactions (physical interactions) between the unlike molecules in the mixtures, and the strength of weak interactions follows the order: (1,4-dioxane + n-octane) > (1,4-dioxane + n-heptane) > (1,4-dioxane + n-hexane). The prevailing physical interactions are found to increase with the increase in temperature. The experimental data of ultrasonic velocity and viscosity have been used to check the applicability of various velocity and viscosity theory models at all temperatures under investigation.