Sorption of 85Sr, 137Cs, and 152Eu from solutions on mixed hexacyanoferrates of potassium and uranyl
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- 作者：S. A. Kulyukhin ; E. P. Krasavina ; M. P. Gorbacheva ; I. A. Rumer ; N. A. Konovalova ; L. V. Mizina and N. V. Tanashchuk
- 关键词：PACS numbers 68.43. ; h
- 刊名：Radiochemistry
- 出版年：2007
- 出版时间：February, 2007
- 年：2007
- 卷：49
- 期：1
- 页码：76-81
- 全文大小：147 KB
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Nuclear Chemistry
Chemistry
Russian Library of Science - 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
- ISSN：1608-3288
文摘
Sorption of 85Sr, 137Cs, and 152Eu from neutral and acidic solutions on mixed hexacyanoferrates of potassium and uranyl K4(UO2)4[Fe(CN)6]3 · 4H2O and K2(UO2)5[Fe(CN)6]4 · 3H2O is studied. The distribution coefficients of 85Sr, 137Cs, and 152Eu between the solid phase of K2(UO2)5[Fe(CN)6]4 · 3H2O and the aqueous phase are determined to be 210±10, 3000±500, and 1100±250 ml g?1, respectively, at a contacting time of 120 min. For solid K4(UO2)4[Fe(CN)6]3 · 4H2O, the respective values are 6670±900, 5600±300, and 3300±250 ml g?1. The 85Sr, 137Cs, and 152Eu distribution coefficients K d between the solid K4(UO2)4[Fe(CN)6]3 · 4H2O and the aqueous phase decrease with decreasing pH.