Facile Synthesis of ZIF-8/ZnO/Polyoxometalate Ternary Composite Materials for Efficient and Rapid Removal of Cationic Organic Dye
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- 作者：Bao Hong ; Lin Liu ; Shi-Ming Wang ; Zheng-Bo Han
- 关键词：Polyoxometalates ; Photocatalysis ; Powder technology ; ZIF ; 8 ; ZnO
- 刊名：Journal of Cluster Science
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：27
- 期：2
- 页码：563-571
- 全文大小：983 KB
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Lin Liu (1)
Shi-Ming Wang (2)
Zheng-Bo Han (1)
1. College of Chemistry, Liaoning University, Shenyang, 110036, People’s Republic of China
2. College of Light Industry, Liaoning University, Shenyang, 110036, People’s Republic of China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Catalysis
Inorganic Chemistry
Physical Chemistry - 出版者：Springer Netherlands
- ISSN：1572-8862
文摘
In this paper, we develop a facile and convenient two-step strategy for preparation of ZIF-8/ZnO/K6P2W18O62 (P2W18) ternary composite materials for the first time. ZIF-8/ZnO are fabricated by a “direct mixing” synthesis strategy and served as the substrate for subsequent P2W18 deposition. Then, ZIF-8/ZnO/P2W18 ternary composite was prepared in P2W18 aqueous solution through electrostatic interaction process. Further, the composites with different loading of P2W18 were achieved by reacting with different concentration of P2W18 aqueous solution. The as-prepared composite materials were characterized and confirmed by powder X-ray diffraction, TEM, EDS, ICP, FT-IR spectra, UV–Vis diffuse reflectance spectroscopy, and electrochemical test. It is noteworthy that the hybrid composites exhibit high efficient activities in the removal of cationic dyes, which could be ascribed to the high adsorption capacity derived from the strong electrostatic interaction between P2W18 and cationic dyes. Based on the investigation, the composites have potential application for waste water purification.