Study on adsorption characteristics of uranyl ions from aqueous solutions using zirconium hydroxide

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• 作者：Hongxue Liu ; Rui Wang ; Heng Jiang ; Hong Gong…
• 关键词：Zirconium hydroxide ; Calcinated product ; Uranyl ions ; Adsorption
• 刊名：Journal of Radioanalytical and Nuclear Chemistry
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：308
• 期：1
• 页码：213-220
• 全文大小：576 KB
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• 作者单位：Hongxue Liu (1)
  Rui Wang (1)
  Heng Jiang (1)
  Hong Gong (1)
  Xiaomeng Wu (1)
  
  1. School of Chemistry and Materials Science, Liaoning Shihua University, Fushun, 113001, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Nuclear Chemistry
  Physical Chemistry
  Nuclear Physics, Heavy Ions and Hadrons
  Diagnostic Radiology
  Inorganic Chemistry
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1588-2780

文摘

The removal of uranyl ions from aqueous solutions using Zr(OH)₄·3.35H₂O (ZH) as adsorbent was investigated using a batch adsorption technique. The maximum removal rate was found as 451.7 mg UO₂ 2+·g−1 ZH. The adsorption capacity and adsorption rate of the calcinated products gradually decreases with increasing calcination temperature. The hydroxyl groups in the zirconium hydroxide play an important role for the adsorption uranyl ions, which agree well with the thermogravimetric analysis of zirconium hydroxide for completely dehydration at 700 °C. The observed data shows that the adsorption process is dependent on surface complexation mechanism.