Synthesis, Luminescent Properties of aza-Boron-Diquinomethene Difluoride Complexes and Their Application for Fluorescent Security Inks
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- 作者：Long Gu ; Rui Liu ; Hong Shi ; Qiang Wang ; Guangliang Song…
- 关键词：Aza ; boron ; diquinomethene ; Difluoride complex ; Carbazole ; Synthesis ; Photoluminescence ; Fluorescent security ink
- 刊名：Journal of Fluorescence
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：26
- 期：2
- 页码：407-412
- 全文大小：662 KB
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Rui Liu (1)
Hong Shi (2)
Qiang Wang (1)
Guangliang Song (1)
Xiaolin Zhu (1)
Shidong Yuan (3)
Hongjun Zhu (1)
1. Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 210009, China
2. Jiangsu Vocational College of Information Technology, Wuxi, 214153, China
3. Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai, 200083, China - 刊物类别：Biomedical and Life Sciences
- 刊物主题：Biomedicine
Biomedicine
Biophysics and Biomedical Physics
Biotechnology
Biochemistry
Analytical Chemistry - 出版者：Springer Netherlands
- ISSN：1573-4994
文摘
Two aza-boron-diquinomethene (aza-BODIQU) complexes bearing phenyl and carbazyl substituents were synthesized and characterized. Their photophysical properties were investigated systematically via spectroscopic and theoretical methods. Both complexes exhibit strong 1π-π* transition absorptions (λ abs = 400–540 nm) and intense fluorescent emissions (λ em = 440–600 nm, Φ PL = 0.93 and 0.78) in CH2Cl2 solution and in solid state at room temperature. Compared to the complex with phenyl groups, the complex bearing carbazyl groups shows significant bathochromic shift in both absorption and emission. This could be attributed to the larger π-electron conjugation of the carbazole unit and intramolecular charge transfer feature from carbazole to aza-BODIQU component. In addition, the complexes exhibit intense photoluminescence and good stability on antacid, anti-alkali and stability in printing ink samples, which makes them potential dopants for the application of fluorescent security inks.