Synthesis of magnetically recyclable MOF-5@SiO2@Fe3O4 catalysts and their catalytic performance of Friedel–Crafts alkylation
详细信息 查看全文
- 作者：Qingyuan Li ; Sai Jiang ; Shengfu Ji ; Da Shi ; Hongkun Li
- 关键词：Magnetic ; MOF ; 5 ; Catalyst ; Friedel–Crafts ; Alkylation
- 刊名：Journal of Porous Materials
- 出版年：2015
- 出版时间：October 2015
- 年：2015
- 卷：22
- 期：5
- 页码：1205-1214
- 全文大小：1,163 KB
- 参考文献：1.D. Alberico, M.E. Scott, M. Lautens, Chem. Rev. 107, 174 (2007)CrossRef
2.B.M. Khadilkar, S.D. Borkar, J. Chem. Technol. Biotechnol. 71, 209 (1998)CrossRef
3.Y. Zhou, X. Li, S. Hou, J. Xu, J. Mol. Catal. A: Chem. 365, 203 (2012)CrossRef
4.G.D. Yadav, S.B. Kamble, Chem. Eng. Res. Des. 90, 1322 (2012)CrossRef
5.Z. Bohstr?m, H. H?relind, K. Holmberg, J. Mol. Catal. A: Chem. 366, 171-78 (2013)CrossRef
6.A. Pineda, A.M. Balu, J.M. Campelo, R. Luque, A.A. Romero, J.C. Serrano-Ruiz, Catal. Today 187, 65 (2012)CrossRef
7.M.J. Gracia, E. Losada, R. Luque, J.M. Campelo, D.J.M. Luna, A.A. MarinasRomero, Appl. Catal. A Gen. 349, 148 (2008)CrossRef
8.J. Dou, H.C. Zeng, J. Am. Chem. Soc. 134, 16235 (2012)CrossRef
9.A. Corma, H. Garcia, F.X.L. Xamena, Chem. Rev. 110, 4606 (2010)CrossRef
10.L. Ma, C. Abney, W. Lin, Chem. Soc. Rev. 38, 1248 (2009)CrossRef
11.S. Neogi, M.K. Sharma, P.K. Bharadwaj, J. Mol. Catal. A: Chem. 299, 1 (2009)CrossRef
12.M. Ranocchiari, J.A. van Bokhoven, Phys. Chem. Chem. Phys. 13, 6388 (2011)CrossRef
13.T.T. Nguyen, N.T.S. Phan, Catal. Lett. 144, 1877 (2014)CrossRef
14.Y.M. Chung, H.Y. Kim, W.S. Ahn, Catal. Lett. 144, 817 (2014)CrossRef
15.D. Esken, X. Zhang, O.I. Lebedev, F. Schroder, R.A. Fischer, J. Mater. Chem. 19, 1314 (2009)CrossRef
16.S. Gao, N. Zhao, M. Shu, S. Che, Appl. Catal. A Gen. 388, 196 (2010)CrossRef
17.F. Zamani, S.M. Hosseini, Catal. Commun. 43, 164 (2014)CrossRef
18.J. Sun, Z.P. Dong, X. Sun, P. Li, F.W. Zhang, W.Q. Hu, H.D. Yang, H.B. Wang, R. Li, J. Mol. Catal. A: Chem. 367, 46 (2013)CrossRef
19.J. Ji, P. Zeng, S. Ji, W. Yang, H. Fei, Y. Li, Catal. Today 158, 305 (2010)CrossRef
20.H. Liu, Z. Jia, S. Ji, Y. Zheng, M. Li, H. Yang, Catal. Today 175, 293 (2011)CrossRef
21.D.J. Tranchemontagne, J.R. Hunt, O.M. Yaghi, Tetrahedron 64, 8553 (2008)CrossRef
22.N. Lock, Y. Wu, M. Christensen, L.J. Cameron, V.K. Peterson, A.J. Bridgeman, C.J. Kepert, B.B. Iversen, J. Phys. Chem. C 114, 16181 (2010)CrossRef
23.L.T.L. Ngyen, T.T. Nguyen, K.D. Nguen, N.T.S. Phan, App. Catal. A Gen. 425-26, 44 (2012)CrossRef
24.D. Saha, S. Deng, J. Colloid Interface Sci. 348, 615 (2010)CrossRef
25.O.M. Yaghi, H. Li, T.L. Groy, J. Am. Chem. Soc. 118, 9096 (1996)CrossRef
26.L. Xu, E.Y. Choi, Y.U. Kwon, Inorg. Chem. Commun. 11, 1190 (2008)CrossRef
27.E. Biemmi, T. Bein, N. Stock, Solid State Sci. 8, 363 (2006)CrossRef
28.S.S. Kaye, A. Dailly, O.M. Yaghi, J.R. Long, J. Am. Chem. Soc. 129, 14176 (2007)CrossRef
29.M. Müller, S. Turner, O.I. Lebedev, Y. Wang, G. van Tendeloo, R.A. Fischer, Eur. J. Inorg. Chem. 12, 1876 (2011)CrossRef
30.S.N. Kim, J. Kim, H.Y. Km, H.Y. Cho, W.S. Ahn, Catal. Today 204, 85 (2013)CrossRef
31.Y. Pan, B. Yuan, Y. Li, D. He, Chem. Commun. 46, 2280 (2010)CrossRef
32.R.G. de Noronha, A.C. Fernandes, C.C. Rom?o, Tetrahedron Lett. 50, 1407 (2009)CrossRef
33.G. Losfeld, V. Escande, P.V. de La Blache, L. L’Huillier, C. Grison, Catal. Today 189, 111 (2012)CrossRef
34.F.L. Morel, M. Ranocchiari, J.A. van Bokhoven, Ind. Eng. Chem. Res. 53, 9120 (2014)CrossRef
35.B. Jager, A. Wermann, P. Scholz, M. Muller, U. Reislohner, A. Stolle, B. Ondruschka, App. Catal. A Gen. 443-44, 87 (2012)CrossRef
36.U. Ravon, M. Saconnet, S. Aguado, M.E. Domine, E. Hanneau, D. Farrusseng, Micro. Meso. Mater. 129, 319 (2010)CrossRef
37.V.R. Choudhary, R. Jha, V.S. Narkhede, J. Mol. Catal. A 239, 76 (2005)CrossRef
38.H. Hentit, K. Bachari, M.S. Ouali, M. Womes, B. Benaichouba, J.C. Jumas, J. Mol. Catal. A 275, 158 (2007)CrossRef - 作者单位：Qingyuan Li (1)
Sai Jiang (1)
Shengfu Ji (1)
Da Shi (1)
Hongkun Li (1)
1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Catalysis
Characterization and Evaluation Materials
Physical Chemistry - 出版者：Springer Netherlands
- ISSN：1573-4854
文摘
Magnetic Fe3O4 particles were synthesized by solvo-thermal method, and then hydrolysis method was used to encapsulate a compact layer of SiO2 on the surface of Fe3O4 particles. Finally, the magnetic MOF-5@SiO2@Fe3O4 catalysts were prepared by in situ coating different contents of MOF-5 on the surface of SiO2@Fe3O4 particles. The as-synthesized samples were characterized by TEM, SEM, XRD, FT-IR, N2 adsorption/desorption, VSM and NH3-TPD. The catalytic activities of the magnetic MOF-5@SiO2@Fe3O4 catalysts for the Friedel–Crafts alkylation of toluene with benzyl chloride were evaluated. The results showed that magnetic MOF-5@SiO2@Fe3O4 catalysts exhibited superparamagnetic property, and could be separated by a magnet from the liquid reaction system. The conversion of toluene was increased gradually with the increase of catalyst contents and reaction temperature, respectively. 97 % conversion of toluene has been achieved by using 26.8 %MOF-5@SiO2@Fe3O4 catalyst at 120 °C for 6 h. Furthermore, electron-donating group, such as –OCH3, and –CH3, exhibited positive effect on the alkylation reaction. Besides, the catalyst could be easily separated from the reaction mixture after the reaction and reused for five times without significant decrease in activity. Keywords Magnetic MOF-5 Catalyst Friedel–Crafts Alkylation