New Member of Organic Ligand Functionalized TMSP: Synthesis, Characterized and Properties of Na15[(MnII(COOH))3(AsW9O _{详细信息    查看全文}

• 作者：Qiong Wu ; Hongping Ju ; Jian Tao ; Zihao Chen ; Jun Li…
• 关键词：Polyoxometalate ; Arsenotungstate ; Organic ligand ; Antitumor activity ; Magnetic properties
• 刊名：Journal of Cluster Science
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：26
• 期：5
• 页码：1811-1820
• 全文大小：602 KB
• 参考文献：1.C. Rudowicz and M. Karbowiak (2015). Coordin. Chem. Rev. 287, 28.CrossRef
  2.R. Liu, S. Li, G. Zhang, A. Dolbecq, P. Mialane, and B. Keita (2014). J. Clust. Sci. 25, 711.CrossRef
  3.B. Zhang, P. Yin, F. Haso, L. Hu, and T. Liu (2014). J. Clust. Sci. 25, 695.CrossRef
  4.D. Y. Du, J. S. Qin, S. L. Li, Z. M. Su, and Y. Q. Lan (2014). Chem. Soc. Rev. 43, 4615.CrossRef
  5.Y. H. Guo and C. W. Hu (2003). J. Clust. Sci. 14, 505.CrossRef
  6.Y. Lv, J. Cheng, A. Steiner, L. Gan, and D. S. Wright (2014). Angew. Chem. Int. Edit. 53, 1934.CrossRef
  7.A. Ziv, A. Grego, S. Kopilevich, L. Zeiri, P. Miro, C. Bo, A. Müller, and I. A. Weinstock (2009). J. Am. Chem. Soc. 131, 6380.CrossRef
  8.C. Daniel and H. Hartl (2009). J. Am. Chem. Soc. 131, 5101.CrossRef
  9.H. J. Bolink, L. Cappelli, S. Cheylan, E. Coronado, R. D. Costa, N. Lardiés, M. K. Nazeeruddin, and E. Ortí (2007). J. Mater. Chem. 17, 5032.CrossRef
  10.M. Vonci and C. Boskovic (2014). Aust. J. Chem. 67, 1542.CrossRef
  11.J. Zhao, Q. Han, D. Shi, L. Chen, P. Ma, J. Wang, and J. Niu (2011). J. Solid State Chem. 184, 2756.CrossRef
  12.G. Rousseau, O. Oms, A. Dolbecq, J. Marrot, and P. Mialane (2011). Inorg. Chem. 50, 7376.CrossRef
  13.S. Reinoso, J. R. Galán-Mascarós, and L. Lezama (2011). Inorg. Chem. 50, 9587.CrossRef
  14.E. M. Limanski, M. Piepenbrink, E. Droste, K. Burgemeister, and B. Krebs (2002). J. Clust. Sci. 13, 369.CrossRef
  15.W. D. Wang, X. X. Li, W. H. Fang, and G. Y. Yang (2011). J. Clust. Sci. 22, 87.CrossRef
  16.N. Zhang, B. Liu, X. M. Liu, T. Ding, Y. Y. Jia, and G. L. Xue (2013). Inorg. Chem. Commun. 29, 30.CrossRef
  17.Y. C. Liu, C. H. Fu, S. T. Zheng, J. W. Zhao, and G. Y. Yang (2013). Dalton Trans. 42, 16676.CrossRef
  18.J. J. Stracke and R. G. Finke (2014). ACS Catal. 4, 79.CrossRef
  19.X. Sang, J. Li, L. Zhang, Z. Wang, W. Chen, Z. Zhu, Z. Su, and E. Wang (2014). ACS Appl. Mater. Interfaces 6, 7876-884.CrossRef
  20.Y. Zhen, B. Liu, L. Li, D. Wang, Y. Ma, H. Hu, S. Gao, and G. Xue (2013). Dalton Trans. 42, 58-2.CrossRef
  21.P. Ma, L. Chen, J. Zhao, W. Wang, J. Wang, and J. Niu (2011). Inorg. Chem. Commun. 14, 415-18.CrossRef
  22.X. X. Li, S. T. Zheng, W. H. Fang, and G. Y. Yang (2011). Inorg. Chem. Commun. 14, 1541-545.CrossRef
  23.Q. Han, P. Ma, J. Zhao, J. Wang, and J. Niu (2011). Inorg. Chem. Commun. 14, 767-70.CrossRef
  24.H. Liu, C.J. Gómez-García, J. Peng, J. Sha, Y. Li and Y. Yan, (2008). Dalton Trans., 6211-6218.
  25.H. Liu, J. Peng, J. Sha, L. Wang, L. Han, D. Chen, and Y. Shen (2009). J. Mol. Struct. 923, 153-61.CrossRef
  26.X. Fang, K. McCallum, H. D. Pratt III, T. M. Anderson, K. Dennis, and M. Luban (2012). Dalton Trans. 41, 9867.CrossRef
  27.X. Fang, P. Kogerler, M. Speldrich, H. Schilder, and M. Luban (2012). Chem. Commun. 48, 1218.CrossRef
  28.X. Fang, M. Speldrich, H. Schilder, R. Cao, K. P. O’Halloran, C. L. Hill, and P. Kogerler (2010). Chem. Commun. 46, 2760-762.CrossRef
  29.X. Fang and P. Kogerler (2008). Chem Commun, 3396.
  30.E. Coronado and C. J. Gomez-Garcia (1998). Chem. Rev. 98, 273.CrossRef
  31.A. Müller and P. K?gerler (1999). Coordin Chem. Rev. 182, 3.CrossRef
  32.S. T. Zheng and G. Y. Yang (2012). Chem. Soc. Rev. 41, 7623.CrossRef
  33.T. Lis (1980). Acta Crystallogr. Sect. B 39, 2042.CrossRef
  34.C. Tourné, A. Revel, G. Tourné, and M. Vendrell (1973). Acad. Soc. Paris Ser. C. 277, 643.
  35.Bruker, SAINT (Bruker AXS Inc., Madison, WI, 2007).
  36.G. M. Sheldrick (2007). Acta Crystallogr. A 64, 112.CrossRef
  37.G. M. Sheldrick SADABS (University of G?ttingen, G?ttingen, Germany, 1996).
  38.L. David, C. Cr?ciun, V. Chis, and R. Tetean (2002). Solid State Commun. 121, 675.CrossRef
  39.H. Liu, L. Xu, G. Gao, F. Li, and N. Jiang (2008). J. Mol. Struct. 878, 124-30.CrossRef
  
• 作者单位：Qiong Wu (1) (3) (4)
  Hongping Ju (2)
  Jian Tao (2)
  Zihao Chen (5)
  Jun Li (2) (3)
  Fuyan Wang (1)
  Qian Cai (1)
  Lifen Sun (1)
  Xinghua Pan (3)
  
  1. Department of Chemical Science and Technology, Kunming University, Kunming, 65200, Yunnan, People’s Republic of China
  3. Stem Cell, Tissue and Organ Engineering Research Center, Kunming General, Hospital of Chinese People’s Liberation Army, Kunming, 650032, People’s Republic of China
  4. Center for Disease Control and Prevention, Chengdu Military Region, Kunming, 650118, People’s Republic of China
  2. Medical School, Kunming University, Kunming, 65200, Yunnan, People’s Republic of China
  5. Hebei Medical University, Shijiazhuang, 050017, Hebei, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Inorganic Chemistry
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1572-8862

文摘

Reaction of [Mn₁₂(CH₃COO)₁₆(H₂O)₄O₁₂]·2CH₃COOH·4H₂O and Na₉[AsW₉O₃₃]·19.5H₂O in aqueous solution leads to the isolation of a new carboxy group decorated TMSP, Na₁₅[(MnII(COOH))₃(AsW₉O₃₃)₂]·15H₂O (1). The structure of 1 was characterized by elemental analysis, thermometric analysis and single crystal X-ray diffraction (Crystal data for 1: Trigonal, P-3, a = 12.8804(4) ?, b = 12.8804(4) ?, c = 30.3501(19) ?, V = 4360.6(3) ?3, Z = 2). Structural analysis reveals that 1 represents the first example of carboxy group decorated arsenotungstate. Antitumor study indicates that compound 1 possesses high antitumor activity against Hela cells. In addition, the magnetic properties of 1 were also investigated. Keywords Polyoxometalate Arsenotungstate Organic ligand Antitumor activity Magnetic properties