Occurrence and hydrogeochemical characteristics of high-fluoride groundwater in Xiji County, southern part of Ningxia Province, China

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• 作者：Chao Wei ; Huaming Guo ; Di Zhang ; Yang Wu…
• 关键词：F− ; Groundwater ; Geochemistry ; Stable isotope ; Water–rock interaction
• 刊名：Environmental Geochemistry and Health
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：38
• 期：1
• 页码：275-290
• 全文大小：2,641 KB
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• 作者单位：Chao Wei (1) (2)
  Huaming Guo (1) (2)
  Di Zhang (1) (2)
  Yang Wu (2)
  Shuangbao Han (3)
  Yonghui An (3)
  Fucun Zhang (3)
  
  1. State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences (Beijing), Beijing, 100083, People’s Republic of China
  2. MOE Key Laboratory of Groundwater Circulation & Environment Evolution and School of Water Resources and Environment, China University of Geosciences (Beijing), Beijing, 100083, People’s Republic of China
  3. Center for Hydrogeology and Environmental Geology, China Geological Survey, Baoding, 071051, Hebei, People’s Republic of China
  
• 刊物类别：Earth and Environmental Science
• 刊物主题：Earth sciences
  Geochemistry
  Atmospheric Protection, Air Quality Control and Air Pollution
  Public Health
  
• 出版者：Springer Netherlands
• ISSN：1573-2983

文摘

High-F− groundwater is widely distributed in Xiji County, which endangers the safety of drinking water. In order to evaluate the key factors controlling the origin and geochemical mechanisms of F− enrichment in groundwater at Xiji County, one hundred and five groundwater samples and sixty-two sediment samples were collected. Fluoride concentration in the groundwater samples ranged from 0.2 to 3.01 mg/L (mean 1.13 mg/L), with 17 % exceeding the WHO drinking water guideline value of 1.5 mg/L and 48 % exceeding the Chinese drinking water guideline value of 1.0 mg/L. High-F− groundwaters were characterized by hydrochemical types of Na–HCO₃ and Na–SO₄·Cl, which were found in Quaternary sediment aquifer and in Tertiary clastic aquifer, respectively. Conditions favorable for F− enrichment in groundwater included weakly alkaline pH (7.2–8.9), low concentration of Ca2+, and high concentrations of HCO₃ − and Na+. Calcite and fluorite were the main minerals controlling F− concentration in groundwaters. The hydrolysis of F-bearing minerals in aquifer sediments was the more important process for F− release in Tertiary clastic aquifer, which was facilitated by long residence time of groundwater, in comparison with Quaternary sediment aquifer. Cation exchange would also play important roles, which removed Ca2+ and Mg2+ and led to more free mobility of F− in groundwater and permitted dissolution of fluorite, especially in Tertiary clastic aquifer. However, evapotranspiration and competing adsorption of B and HCO₃ − were the more important processes for F− enrichment in Quaternary groundwater. Groundwater in Lower Cretaceous aquifer had relatively low F− concentration, which was considered to be the potential drinking water resource. Keywords F− Groundwater Geochemistry Stable isotope Water–rock interaction