Encapsulation of metal layers within metal–organic frameworks as hybrid thin films for selective catalysis

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• 作者：Zhiling Xu ; Weina Zhang ; Jiena Weng ; Wei Huang ; Danbi Tian ; Fengwei Huo
• 关键词：metal–organic frameworks ; catalysis ; hybrid thin films ; metal layers ; composition
• 刊名：Nano Research
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：9
• 期：1
• 页码：158-164
• 全文大小：1,559 KB
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• 作者单位：Zhiling Xu (1) (2)
  Weina Zhang (1)
  Jiena Weng (1)
  Wei Huang (1)
  Danbi Tian (2)
  Fengwei Huo (1)
  
  1. Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (Nanjing Tech), 30 South Puzhu Road, Nanjing, 211816, China
  2. College of Science, Nanjing Tech University, 30 South Puzhu Road, Nanjing, 211816, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chinese Library of Science
  Chemistry
  Nanotechnology
  
• 出版者：Tsinghua University Press, co-published with Springer-Verlag GmbH
• ISSN：1998-0000

文摘

A facile encapsulation strategy for the preparation of metal layer/metal–organic framework (metal/MOF) hybrid thin films, by alternately growing MOF thin films and sputter-coating metal layers, is reported. The controlled species of the MOF thin films and metal layers, as well as the designed thickness of MOF thin films, endow the resulting hybrid thin films with improved functional and design flexibility. Importantly, the metal/MOF hybrid thin films, with well-defined sandwich structures, exhibit excellent selective catalytic activity, derived from MOFs acting as molecular sieves and the metal layers providing active sites.