Synthesis of silicalite-poly(furfuryl alcohol) composite membranes for oxygen enrichment from air

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• 作者：Li He (1)
  Dan Li (1)
  Kun Wang (1)
  Akkihebbal K Suresh (2)
  Jayesh Bellare (2)
  Tam Sridhar (1)
  Huanting Wang (1)
  
• 关键词：poly(furfuryl alcohol) ; silicalite ; composite membrane ; air separation
• 刊名：Nanoscale Research Letters
• 出版年：2011
• 出版时间：December 2011
• 年：2011
• 卷：6
• 期：1
• 全文大小：808KB
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• 作者单位：Li He (1)
  Dan Li (1)
  Kun Wang (1)
  Akkihebbal K Suresh (2)
  Jayesh Bellare (2)
  Tam Sridhar (1)
  Huanting Wang (1)
  
  1. Department of Chemical Engineering, Monash University, Clayton, Victoria, 3800, Australia
  2. Department of Chemical Engineering, Indian Institute of Technology Bombay, Bombay, Maharashtra, 400076, India
  
• ISSN：1556-276X

文摘

Silicalite-poly(furfuryl alcohol) [PFA] composite membranes were prepared by solution casting of silicalite-furfuryl alcohol [FA] suspension on a porous polysulfone substrate and subsequent in situ polymerization of FA. X-ray diffraction, nitrogen sorption, thermogravimetric analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy were used to characterize silicalite nanocrystals and silicalite-PFA composite membranes. The silicalite-PFA composite membrane with 20 wt.% silicalite loading exhibits good oxygen/nitrogen selectivity (4.15) and high oxygen permeability (1,132.6 Barrers) at 50°C. Silicalite-PFA composite membranes are promising for the production of oxygen-enriched air for various applications.