One-step fabrication of ZIF-8/polymer composite spheres by a phase inversion method for gas adsorption

详细信息    查看全文

• 作者：Lunxi Li (1)
  Jianfeng Yao (1)
  Penny Xiao (2)
  Jin Shang (2)
  Yi Feng (1)
  Paul A. Webley (2)
  Huanting Wang (1)
  
• 关键词：Polysulfone ; Zeolitic imidazolate framework ; Composite sphere ; Gas adsorption
• 刊名：Colloid & Polymer Science
• 出版年：2013
• 出版时间：November 2013
• 年：2013
• 卷：291
• 期：11
• 页码：2711-2717
• 全文大小：551KB
• 参考文献：1. Li JR, Ma YG, McCarthy MC, Sculley J, Yu JM, Jeong HK, Balbuena PB, Zhou HC (2011) Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks. Coord Chem Rev 255:1791鈥?823 CrossRef
  2. Zhao ZX, Li Z, Lin YS (2009) Adsorption and diffusion of carbon dioxide on metal-organic framework (MOF-5). Ind Eng Chem Res 48:10015鈥?0020 CrossRef
  3. James SL (2003) Metal-organic frameworks. Chem Soc Rev 32:276鈥?88 CrossRef
  4. Czaja AU, Trukhan N, Muller U (2009) Industrial applications of metal-organic frameworks. Chem Soc Rev 38:1284鈥?293 CrossRef
  5. Smaldone RA, Forgan RS, Furukawa H, Gassensmith JJ, Slawin AMZ, Yaghi OM, Stoddart JF (2010) Metal-organic frameworks from edible natural products. Angew Chem Int Ed 49:8630鈥?634 CrossRef
  6. Park KS, Ni Z, Cote AP, Choi JY, Huang RD, Uribe-Romo FJ, Chae HK, O鈥橩eeffe M, Yaghi OM (2006) Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. Proc Natl Acad Sci U S A 103:10186鈥?0191 CrossRef
  7. Bux H, Liang F, Li Y, Cravillon J, Wiebcke M, Caro J (2009) Zeolitic imidazolate framework membrane with molecular sieving properties by microwave-assisted solvothermal synthesis. J Am Chem Soc 131:16000鈥?6001 CrossRef
  8. Li Y, Liang F, Bux H, Yang W, Caro J (2010) Zeolitic imidazolate framework ZIF-7 based molecular sieve membrane for hydrogen separation. J Membr Sci 354:48鈥?4 CrossRef
  9. Cravillon J, Muenzer S, Lohmeier SJ, Feldhoff A, Huber K, Wiebcke M (2009) Rapid room-temperature synthesis and characterization of nanocrystals of a prototypical zeolitic imidazolate framework. Chem Mater 21:1410鈥?412 CrossRef
  10. Liu DF, Wu YB, Xia QB, Li Z, Xi HX (2013) Experimental and molecular simulation studies of carbon dioxide adsorption on zeolitic imidazolate frameworks: ZIF-8 and amine-modified. Adsorption 19:25鈥?7 CrossRef
  11. Yao JF, Chen RZ, Wang K, Wang HT (2013) Direct synthesis of zeolitic imidazolate framework-8/chitosan composites in chitosan hydrogels. Microporous Mesoporous Mater 165:200鈥?04 CrossRef
  12. Fairen-Jimenez D, Moggach SA, Wharmby MT, Wright PA, Parsons S, Duren T (2011) Opening the gate: framework flexibility in ZIF-8 explored by experiments and simulations. J Am Chem Soc 133:8900鈥?902 CrossRef
  13. O鈥橬eill LD, Zhang HF, Bradshaw D (2010) Macro-/microporous MOF composite beads. J Mater Chem 20:5720鈥?726 CrossRef
  14. Thornton AW, Dubbeldam D, Liu MS, Ladewig BP, Hill AJ, Hill MR (2012) Feasibility of zeolitic imidazolate framework membranes for clean energy applications. Energy Environ Sci 5:7637鈥?646 CrossRef
  15. Li LX, Yao JF, Chen RZ, He L, Wang K, Wang HT (2013) Infiltration of precursors into a porous alumina support for ZIF-8 membrane synthesis. Microporous Mesoporous Mater 168:15鈥?8 CrossRef
  16. Yao JF, Dong DH, Li D, He L, Xu GS, Wang HT (2011) Contra-diffusion synthesis of ZIF-8 films on a polymer substrate. Chem Commun 47:2559鈥?561 CrossRef
  17. Aguado S, Canivet J, Farrusseng D (2010) Facile shaping of an imidazolate-based MOF on ceramic beads for adsorption and catalytic applications. Chem Commun 46:7999鈥?001 CrossRef
  18. Zhang H, Cooper AI (2002) Synthesis of monodisperse emulsion-templated polymer beads by oil-in-water-in-oil (O/W/O) sedimentation polymerization. Chem Mater 14:4017鈥?020 CrossRef
  19. Zhang HF, Cooper AI (2005) Synthesis and applications of emulsion-templated porous materials. Soft Matter 1:107鈥?13 CrossRef
  20. Zhou D, Zhang LN, Zhou JP, Guo SL (2004) Cellulose/chitin beads for adsorption of heavy metals in aqueous solution. Water Res 38:2643鈥?650 CrossRef
  21. Loeb S, Sourirajan S (1963) Sea water demineralization by means of an osmotic membrane. Adv Chem Ser 38:117鈥?32 CrossRef
  22. Yao JF, Wang K, Ren MR, Liu JZ, Wang HT (2012) Phase inversion spinning of ultrafine hollow fiber membranes through a single orifice spinneret. J Membr Sci 421:8鈥?4 CrossRef
  23. Mulijani S, Mulanawati A (2012) Enhanced performance of asymmertic polystyrene membrane by incorporation of pluronic F127 and its application for pervaporation separation. Procedia Chem 4:360鈥?66 CrossRef
  24. Yao JF, He M, Wang K, Chen RZ, Zhong ZX, Wang HT (2013) High-yield synthesis of zeolitic imidazolate frameworks from stoichiometric metal and ligand precursor aqueous solutions at room temperature. CrystEngComm 15:3601鈥?606 CrossRef
  25. Guillen GR, Pan YJ, Li MH, Hoek EMV (2011) Preparation and characterization of membranes formed by nonsolvent induced phase separation: a review. Ind Eng Chem Res 50:3798鈥?817 CrossRef
  26. Song QL, Nataraj SK, Roussenova MV, Tan JC, Hughes DJ, Li W, Bourgoin P, Alam MA, Cheetham AK, Al-Muhtaseb SA, Sivaniah E (2012) Zeolitic imidazolate framework (ZIF-8) based polymer nanocomposite membranes for gas separation. Energy Environ Sci 5:8359鈥?369 CrossRef
  
• 作者单位：Lunxi Li (1)
  Jianfeng Yao (1)
  Penny Xiao (2)
  Jin Shang (2)
  Yi Feng (1)
  Paul A. Webley (2)
  Huanting Wang (1)
  
  1. Department of Chemical Engineering, Monash University, Melbourne, VIC, 3800, Australia
  2. Department of Chemical and Biomolecular Engineering, Melbourne School of Engineering, University of Melbourne, Melbourne, VIC, 3010, Australia
  
• ISSN：1435-1536

文摘

This paper reports a phase inversion method for the preparation of macroporous polysulfone (PS) composite spheres through a single orifice spinneret. Surfactant F127 was pre-added in the polymer solution as a surface pore-forming agent, and different amount of zeolitic imidazolate framework-8 (ZIF-8) particles were incorporated to form the ZIF-8/polysulfone (ZIF-8/PS)-composite spheres. ZIF-8 and polymer acted as the adsorbent and binder in the final composite spheres, respectively. The fabrication conditions, such as the types of the surfactant, the amount of the surfactant, and ZIF-8 added in the polymer solution, were investigated. Nitrogen and carbon dioxide sorption analysis indicated the ZIF-8/PS composite spheres had similar properties as the pure ZIF-8 particles, and the active sites of ZIF-8 in the polymer composites were well exposed. The composite spheres exhibited advantages of easy handling and recycling over ZIF-8 particles, and this phase inversion method can be extended to prepare other polymer composite spheres.