Preparation and properties of polyacrylonitrile fibers with guanidine groups

详细信息    查看全文

• 作者：Chengran Yang ; Biao Wang ; Yumei Zhang ; Huaping Wang
• 关键词：Surface modification ; Polyacrylonitrile fiber ; Polyhexamethylene Guanidine hydrochloride ; Dyeability ; Hydrophilicity
• 刊名：Fibers and Polymers
• 出版年：2015
• 出版时间：August 2015
• 年：2015
• 卷：16
• 期：8
• 页码：1611-1617
• 全文大小：569 KB
• 参考文献：1.M. Lewin and E. M. Pearce, “Handbook of Fiber Chemistry- 2nd ed., pp.905-24, CRC Press, New York, 1998.
  2.C. W. Nam, Y. H. Kim, and S. W. Ko, J. Appl. Polym. Sci., 82, 1620 (2001).CrossRef
  3.J. Masson, “Acrylic Fiber Technology and Applications- 1st ed., pp.40-7, CRC Press, New York, 1995.
  4.P. Bajaj and S. Kumari, J. Macromol. Sci., Polym. Rev., 27, 181 (1987).CrossRef
  5.L. Wang, J. Xie, L. Gu, and G. Sun, Polym. Bull., 56, 247 (2006).CrossRef
  6.Y. Sawa and M. Hoten, Color. Technol., 117, 171 (2001).CrossRef
  7.F. Q. Nie, Z. K. Xu, Y. Q. Ming, R. Q. Kou, Z. M. Liu, and S. Y. Wang, Desalination, 160, 43 (2004).CrossRef
  8.F.-Q. Nie, Z.-K. Xu, Q. Yang, J. Wu, and L.-S. Wan, J. Membr. Sci., 235, 147 (2004).CrossRef
  9.P. Bajaj, D. K. Paliwal, and A. K. Gupta, J. Appl. Polym. Sci., 49, 823 (1993).CrossRef
  10.P. Bajaj, K. Sen, and S. H. Bahrami, J. Appl. Polym. Sci., 59, 1539 (1996).CrossRef
  11.C. Hou, C. Ji, and L. Ying, J. Appl. Polym. Sci., 103, 3920 (2007).CrossRef
  12.M. Wang, L.-G. Wu, J.-X. Mo, and C.-J. Gao, J. Membr. Sci., 274, 200 (2006).CrossRef
  13.T. Godjevargova, V. Konsulov, A. Dimov, and N. Vasileva, J. Membr. Sci., 172, 279 (2000).CrossRef
  14.N. Pekel, Z. M. O. Rzaev, and O. Güven, Macromol. Chem. Phys., 205, 1088 (2004).CrossRef
  15.T. Groth, B. Seifert, G. Malsch, W. Albrecht, D. Paul, A. Kostadinova, N. Krasteva, and G. Altankov, J. Biomed. Mater. Res., 61, 290 (2002).CrossRef
  16.N. Krasteva, U. Harms, W. Albrecht, B. Seifert, M. Hopp, G. Altankov, and T. Groth, Biomaterials, 23, 2467 (2002).CrossRef
  17.K. W. Broadhead and P. A. Tresco, J. Membr. Sci., 147, 235 (1998).CrossRef
  18.Y. Ren, B. Cheng, L. Xu, A. Jiang, and Y. Lu, J. Appl. Polym. Sci., 115, 1489 (2010).CrossRef
  19.P. Wyman, V. Crook, J. Ebdon, B. Hunt, and P. Joseph, Polym. Int., 55, 764 (2006).CrossRef
  20.E. Jakab and M. Blazsó, J. Anal. Appl. Pyrolysis, 64, 263 (2002).CrossRef
  21.Z. Xu, Y. Zhang, W. Hong, and S. Zheng, Polym. Plast. Technol. Eng., 48, 280 (2009).CrossRef
  22.T. V. Sreekumar, T. Liu, B. G. Min, H. Guo, S. Kumar, R. H. Hauge, and R. E. Smalley, Adv. Mater., 16, 58 (2004).CrossRef
  23.S. Moon and T. Emrick, Polymer, 54, 1813 (2013).CrossRef
  24.Y. Mo, M. Yang, Z. Lu, and F. Huang, Compos. Pt. A-Appl. Sci. Manuf., 54, 153 (2013).CrossRef
  25.Q. Wang, Y. Du, Q. Feng, F. Huang, K. Lu, J. Liu, and Q. Wei, J. Appl. Polym. Sci., 128, 1152 (2013).CrossRef
  26.G. Prusty and S. K. Swain, Mater. Sci. Semicond. Process., 16, 2039 (2013).CrossRef
  27.W. Pan, S. Yang, G. Li, and J. Jiang, Int. J. Polym. Mater. Polym. Biomater., 54, 21 (2005).CrossRef
  28.P. Raghavan, X. Zhao, C. Shin, D. H. Baek, J. W. Choi, J. Manuel, M. Y. Heo, J. H. Ahn, and C. Nah, J Power Sources, 195, 6088 (2010).CrossRef
  29.M. C. Yang and T. Y. Liu, J. Membr. Sci., 226, 119 (2003).CrossRef
  30.R. Prasanth, V. Aravindan, and M. Srinivasan, J. Power Sources, 202, 299 (2012).CrossRef
  31.S. H. Goh, S. Y. Lee, Y. T. Yeo, X. Zhou, and K. L. Tan, Macromol. Rapid Commun., 20, 148 (1999).CrossRef
  32.N. Nishioka, Y. Nakano, T. Hirota, N. Fujiwara, and M. Uno, J. Appl. Polym. Sci., 59, 1203 (1996).CrossRef
  33.D. Ingildeev, F. Hermanutz, K. Bredereck, and F. Effenberger, Macromol. Mater. Eng., 297, 585 (2012).CrossRef
  34.C. W. Nam, Y. H. Kim, and S. W. Ko, J. Appl. Polym. Sci., 74, 2258 (1999).CrossRef
  35.K. Saeed, S. Y. Park, and T. J. Oh, J. Appl. Polym. Sci., 121, 869 (2011).CrossRef
  36.N. Horzum, T. Shahwan, O. Parlak, and M. M. Demir, Chem. Eng. J., 213, 41 (2012).CrossRef
  37.F. Huang, Y. Xu, S. Liao, D. Yang, Y. L. Hsieh, and Q. Wei, Materials, 6, 969 (2013).CrossRef
  38.M. E. McComb and H. D. Gesser, J. Appl. Polym. Sci., 65, 1175 (1997).CrossRef
  39.V. Popescu and E. I. Muresan, Ind. Eng. Chem. Res., 52, 13252 (2013).CrossRef
  40.C. Feng, J. Xu, M. Li, Y. Tang, and C. Gao, J. Membr. Sci., 451, 103 (2014).CrossRef
  41.S. Senthilkumar, S. Rajesh, A. Jayalakshmi, and D. Mohan, Sep. Purif. Technol., 107, 297 (2013).CrossRef
  42.F. A. Kantouch and A. A. El-Sayed, J. Appl. Polym. Sci., 119, 2595 (2011).CrossRef
  43.V. Babu, S. Pasha, G. Gupta, C. B. Majumdar, and B. Choudhury, Fiber. Polym., 15, 24 (2014).CrossRef
  44.S. Gerli, D. Rossetti, and G. C. Di Renzo, Eur. Rev. Med. Pharmacol. Sci., 7, 127 (2003).
  45.K. Hiti, J. Walochnik, E. M. Haller-Schober, C. Faschinger, and H. Asp?ck, Br. J. Ophthalmol., 86, 144 (2002).CrossRef
  46.J. M. Kusnetsov, A. I. Tulkki, H. E. Ahonen, and P. J. Martikainen, J. Appl. Microbiol., 82, 763 (1997).CrossRef
  47.A. Welk, C. H. Splieth, G. Schmidt-Martens, C. Schwahn, T. Kocher, A. Kramer, and M. Rosin, J. Clin. Periodontol., 32, 499 (2005).CrossRef
  48.Y. Guan, H. Xiao, H. Sullivan, and A. Zheng, Carbohydr. Polym., 69, 688 (2007).CrossRef
  49.S. Li, M. Xiao, Y. Guan, D. Wei, H. Xiao, and A. Zheng, Eur. Polym. J., 48, 362 (2012).CrossRef
  50.G. Li, L. F. Hao, H.
• 作者单位：Chengran Yang (1)
  Biao Wang (1)
  Yumei Zhang (1)
  Huaping Wang (1)
  
  1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai, 201620, P. R. China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  
• 出版者：The Korean Fiber Society
• ISSN：1875-0052

文摘

The polyacrylonitrile (PAN) fibers grafted with guanidine groups were prepared by hydrolyzing with sodium hydroxide solution followed by reacting with polyhexamethylene guanidine hydrochloride (PHGC). The grafting degree could be controlled by changing the treatment time of hydrolyzed PAN fibers with PHGC. The chemical composition and morphology of the modified PAN fibers were characterized by Fourier transform infrared spectroscopy (FTIR), Elemental analysis (EA), X-ray photoelectric spectroscopy (XPS) and scanning electron microscope (SEM). The results showed that the guanidine groups were effectively grafted on the fibers. The water contact angle of the surface modified PAN fibers was reduced and moisture regain was improved significantly with the immobilization of PHGC on the fibers. Furthermore, the modified PAN fibers exhibited favorable acid dyeability at low temperature (50 °C) over a wide pH range and good mechanical properties. The simple and applicable synthesis process provides a new avenue for modification of PAN fibers with improved hydrophilicity and acid dyeability. Keywords Surface modification Polyacrylonitrile fiber Polyhexamethylene Guanidine hydrochloride Dyeability Hydrophilicity