Degradation of Co3O4 anode in rechargeable lithium-ion battery: a semi-empirical approach to the effect of conducting material content
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- 作者：Woo-Sung Choi ; Sooyeon Hwang ; Wonyoung Chang…
- 关键词：Conducting material ; Solid electrolyte interface ; Co3O4 ; Lithium ; ion battery
- 刊名：Journal of Solid State Electrochemistry
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：20
- 期：2
- 页码：345-352
- 全文大小：1,058 KB
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Sooyeon Hwang (2)
Wonyoung Chang (2)
Heon-Cheol Shin (1)
1. School of Materials Science and Engineering, Pusan National University, Busan, 609-735, Korea
2. Center for Energy Convergence, Korea Institute of Science and Technology, Seoul, 136-791, Korea - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Physical Chemistry
Analytical Chemistry
Industrial Chemistry and Chemical Engineering
Characterization and Evaluation Materials
Condensed Matter
Electronic and Computer Engineering - 出版者：Springer Berlin / Heidelberg
- ISSN：1433-0768
文摘
A large amount of conducting materials has typically been blended with transition metal oxides (MxOy, M = Fe, Co, Ni, Cu), and their electrochemical properties as the anode in lithium-ion batteries have been studied. Here, we report that a higher content of the conducting material results in poorer cycling stability of Co3O4. From the analysis of the cumulative irreversible capacity loss, a high content of conducting material is proven to promote irreversible electron consumption for the growth of a polymeric surface layer which is the origin of degradation. Furthermore, its formation is mathematically modeled on the basis of the Butler–Volmer relation. From the physical parameters of the polymeric surface layer determined by fitting the model to the experimental data, the degradation mechanism of Co3O4 is discussed. Keywords Conducting material Solid electrolyte interface Co3O4 Lithium-ion battery