Effect of heteropolyacids on the hydrocarboxylation of styrene: comparative study on hydrocarboxylation and hydroesterification reactions

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• 作者：Bassam El Ali
• 关键词：palladium(II) ; heteropolyacids ; styrene ; Hydrocarboxylation ; acid derivatives ; hydroesterification
• 刊名：Reaction Kinetics and Catalysis Letters
• 出版年：2002
• 出版时间：2002
• 年：2002
• 卷：77
• 期：2
• 页码：227-236
• 全文大小：61 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Sciences
  Catalysis
  Physical Chemistry
  Industrial Chemistry and Chemical Engineering
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1588-2837

文摘

The hydrocarboxylation and the hydroesterification of styrene was studied in the presence of PdCl₂(PPh₃)₂ as a catalyst. The effect of the addition of the heteropolyacids of a general formula H_3+nPMo_12-nV_nO₄₀ (HPA-n, n=1-4) on the hydrocarboxylation and the hydroesterification of styrene was considered.