Use of heterogenized metal complexes in hydrogenation reactions: comparison of hydrogenation and CTH reactions

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• 作者：Peter Bata ; ágnes Zsigmond ; Mihály Gyémánt…
• 关键词：Catalytic transfer hydrogenation ; Iron–phthalocyanine catalyst ; Chemoselectivity
• 刊名：Research on Chemical Intermediates
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：41
• 期：12
• 页码：9281-9294
• 全文大小：553 KB
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• 作者单位：Peter Bata (1)
  ágnes Zsigmond (1)
  Mihály Gyémánt (1)
  Ambrus Czeglédi (1)
  Peter Kluson (2)
  
  1. Department of Organic Chemistry, University of Szeged, Dóm tér 8, Szeged, 6720, Hungary
  2. Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, Rozvojova 135, 165 02, Prague, Czech Republic
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1568-5675

文摘

In the fine chemicals industry the preference for heterogeneous over homogeneous catalysts is well known. However, the activity and selectivity of heterogeneous metal complexes are usually better than those of their homogeneous counterparts. There has, consequently, been an increasing demand for heterogenized metal complexes which combine the advantages of both types of catalyst. In the production of fine chemicals, selectivity is probably its most important property of a catalyst. Chemoselectivity, regioselectivity, and enantioselectivity are very important in the synthesis of fine chemicals. Several examples of hydrogenation with heterogenized metal complexes have been studied, with emphasis on selectivity. Catalytic transfer hydrogenation is also discussed, as an alternative to classical hydrogenation. Keywords Catalytic transfer hydrogenation Iron–phthalocyanine catalyst Chemoselectivity