Synthesis and application of polyurethane basic organic-inorganic hybrid materials as highly hydrophobic coatings

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• 作者：Chen-Han Yang ; Yun-Wen Pan ; Jian-Jhang Guo ; Tai-Horng Young…
• 关键词：Highly hydrophobic coatings ; Polyurethane ; Colloidal silica ; Polybutadiene
• 刊名：Journal of Polymer Research
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：23
• 期：2
• 全文大小：1,065 KB
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• 作者单位：Chen-Han Yang (1)
  Yun-Wen Pan (2)
  Jian-Jhang Guo (2)
  Tai-Horng Young (1) (3)
  Wen-Yen Chiu (1) (2)
  Kuo-Huang Hsieh (1) (2) (4)
  
  1. Institute of Polymer Science and Engineering, National Taiwan University, Taipei, 106, Taiwan
  2. Department of Chemical Engineering, National Taiwan University, Taipei, 106, Taiwan
  3. Institute of Biomedical Engineering, National Taiwan University, Taipei, 100, Taiwan
  4. Institute of Polymer Science and Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Rd., Taipei, 10617, Taiwan
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  Industrial Chemistry and Chemical Engineering
  Characterization and Evaluation Materials
  
• 出版者：Springer Netherlands
• ISSN：1572-8935

文摘

In this study, we report a simple method which via modified-colloid silica blending with polybutadiene-base polyurethane to form a hydrophobic composite material. The hydrophobic film is characterized by optical microscopy, scanning electron microscopy (SEM), and water contact angle. Desired surface roughness was obtained by hydrophobic silica tuning the microstructures that contact angle approach 150.1o when contain ODTMS/colloid silica =90/10. With the increase of the blended ratio of modified silica with the PBU, we also could obtain the rough surface, and increased its hydrophobicity.