Role of Calcination Temperature on the Hydrotalcite Derived MgO–Al2O3 in Converting Ethanol to Butanol
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- 作者：Karthikeyan K. Ramasamy ; Michel Gray ; Heather Job ; Daniel Santosa…
- 关键词：Ethanol condensation ; Guerbet ; Hydrotalcite ; Butanol ; Mixed oxide ; MgO–Al2O3
- 刊名：Topics in Catalysis
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：59
- 期：1
- 页码：46-54
- 全文大小：774 KB
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Michel Gray (1)
Heather Job (1)
Daniel Santosa (1)
Xiaohong Shari Li (2)
Arun Devaraj (3)
Abhi Karkamkar (1)
Yong Wang (1) (2) (4)
1. Chemical and Biological Process Development Group, Pacific Northwest National Laboratory, Richland, WA, 99352, USA
2. Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA, 99352, USA
3. Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA, 99352, USA
4. The Gene and Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University, Pullman, WA, 99164, USA - 刊物主题：Catalysis; Physical Chemistry; Pharmacy; Industrial Chemistry/Chemical Engineering; Characterization and Evaluation of Materials;
- 出版者：Springer US
- ISSN：1572-9028
文摘
In the base catalyzed ethanol condensation reactions, the calcined MgO–Al2O3 derived hydrotalcites used broadly as catalytic material and the calcination temperature plays a big role in determining the catalytic activity. The characteristics of the hydrotalcite material treated between catalytically relevant temperatures 450 and 800 °C have been studied with respect to the physical, chemical, and structural properties and compared with catalytic activity testing. With the increasing calcination temperature, the total measured catalytic basicity dropped linearly with the calcination temperature and the total measured acidity stayed the same for all the calcination temperatures except 800 °C. However, the catalyst activity testing does not show any direct correlation between the measured catalytic basicity and the catalyst activity to the ethanol condensation reaction to form 1-butanol. The highest ethanol conversion of 44 % with 1-butanol selectivity of 50 % was achieved for the 600 °C calcined hydrotalcite material.