Terahertz time-domain and Fourier-transform infrared spectroscopy of traditional Korean pigments

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• 作者：Taeyoon Hong (1)
  Kyujin Choi (1)
  Taewoo Ha (1)
  Byung Cheol Park (1)
  Kyung Ik Sim (1)
  Jong Hyeon Kim (1)
  Jae Hoon Kim (1)
  Jy Eun Kwon (2)
  Sanghyun Lee (3)
  Dai Ill Kang (4)
  Han Hyoung Lee (4)
  
• 关键词：Pigments ; Terahertz time ; domain spectroscopy (THz ; TDS) ; Fourier ; transform infrared spectroscopy (FTIRS) ; Refractive index ; Extinction coefficient ; Absorption coefficient
• 刊名：Journal of the Korean Physical Society
• 出版年：2014
• 出版时间：March 2014
• 年：2014
• 卷：64
• 期：5
• 页码：727-731
• 全文大小：2,573 KB
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• 作者单位：Taeyoon Hong (1)
  Kyujin Choi (1)
  Taewoo Ha (1)
  Byung Cheol Park (1)
  Kyung Ik Sim (1)
  Jong Hyeon Kim (1)
  Jae Hoon Kim (1)
  Jy Eun Kwon (2)
  Sanghyun Lee (3)
  Dai Ill Kang (4)
  Han Hyoung Lee (4)
  
  1. Department of Physics, Yonsei University, Seoul, 120-749, Korea
  2. Department of Traditional Arts and Crafts, Korea National University of Cultural Heritage, Buyeo, 323-812, Korea
  3. Department of Intangible Cultural Heritage, Graduate School of Cultural Assets and Convergence, Korea National University of Cultural Heritage, Buyeo, 323-812, Korea
  4. Department of Conservation Science, Korea National University of Cultural Heritage, Buyeo, 323-812, Korea
  
• ISSN：1976-8524

文摘

Representative traditional Korean pigments (oyster shell white [hobun], massicot [miltaseung], indigo [jjok], azurite [seokcheong], malachite [seokrok], and red lead [yeondan]) have been studied with terahertz time-domain spectroscopy (THz-TDS) and Fourier-transform infrared spectroscopy (FTIRS) over the spectral region of 0.1-.5 THz. Both the refractive index n and the extinction coefficient k were simultaneously and independently determined in the terahertz region without a Kramers-Kronig analysis while the absoprtion coefficient spectra were acquired in the infrared region. All pigments studied in the present work exhibited a set of characteristic absorption peaks unique to the pigment species in addition to a background that increased with increasing frequency. Our study demonstrates that terahertz and infrared techniques can be useful identification and diagnostic tools for the traditional Korean pigments used in heritage buildings and artworks.