Functionalized polynorbornenes with fragments of cholic acid and luminophore complexes of iridium(III) and copper(I) in side chains. Synthesis and photophysical properties
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- 作者：E. O. Platonova ; A. I. Il’icheva ; Yu. P. Parshina…
- 关键词：functionalized polynorbornenes ; metathesis polymerization ; cholic acid ; iridium ; containing polymers ; copper ; containing polymers ; photophysical properties
- 刊名：Russian Journal of General Chemistry
- 出版年：2016
- 出版时间：September 2016
- 年：2016
- 卷：86
- 期：9
- 页码：2081-2087
- 全文大小：272 KB
- 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Chemistry
Russian Library of Science - 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
- ISSN：1608-3350
- 卷排序：86
文摘
Copolymers containing fragments of cholic acid and luminophore complexes of iridium(III) and copper(I) in the side chains have been synthesized by metathesis polymerization. Photophysical properties of the obtained compounds have been investigated. Iridium-containing copolymers demonstrate intense photoluminescence of green, bluish-green and red colors. Copper-containing copolymers generate radiation of green and yellow-green colors. The color of photoluminescence of the metal-containing polymers is determined by the nature of copper(I) and iridium(III) complexes bonded to polymer chain.