Zeolitic Imidazolate Frameworks: Synthesis, Functionalization, and Catalytic/Adsorption Applications

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• 作者：Samiran Bhattacharjee (1)
  Min-Seok Jang (1)
  Hee-Jin Kwon (1)
  Wha-Seung Ahn (1)
  
• 关键词：Zeolitic imidazolate frameworks (ZIFs) ; ZIF ; 8 ; Synthesis ; Functionalization ; Heterogeneous catalysis ; Adsorption
• 刊名：Catalysis Surveys from Asia
• 出版年：2014
• 出版时间：December 2014
• 年：2014
• 卷：18
• 期：4
• 页码：101-127
• 全文大小：3,628 KB
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• 作者单位：Samiran Bhattacharjee (1)
  Min-Seok Jang (1)
  Hee-Jin Kwon (1)
  Wha-Seung Ahn (1)
  
  1. Department of Chemistry and Chemical Engineering, Inha University, Incheon, 402-751, South Korea
  
• ISSN：1574-9266

文摘

Zeolitic imidazolate frameworks (ZIFs) are comprised of transition metal ions (Zn, Co) and a range of imidazolate linkers in a tetrahedral coordination similar to that in crystalline aluminosilicate zeolites. The high surface area, tunable nanoporosity that can be subject to functionalization and the excellent thermal/chemical stability of ZIFs are attractive for heterogeneous catalysis and selective gas adsorption/separation. This review presents the current trends in synthesis, surface modification and catalytic reactions/adsorption of ZIF-based materials with particular emphasis on ZIF-8, which is the most widely studied structure among ZIFs.