Synthesis of N-(2,2,2-trichloro-1-hydroxyethyl)aldimines and their derivatives

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• 作者：Yu. N. Firsova ; S. R. Engel ; N. A. Lozinskaya ; S. E. Sosonyuk…
• 关键词：2 ; 2 ; 2 ; trichloro ; 1 ; (arylideneamino)ethanols ; N ; (2 ; 2 ; 2 ; trichloro ; 1 ; hydroxyethyl)aldimines ; cyclopropenone ; silylation ; acylation
• 刊名：Russian Chemical Bulletin
• 出版年：2015
• 出版时间：January 2015
• 年：2015
• 卷：64
• 期：1
• 页码：76-82
• 全文大小：306 KB
• 参考文献：1.N. A. Lozinskaya, S. E. Sosonyuk, Yu. N. Firsova, M. V. Proskurnina, N. S. Zefirov, Russ. Chem. Bull. (Int. Ed.), 2011, 60, 1989 [Izv. Akad. Nauk, Ser. Khim., 2011, 1955].CrossRef
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• 作者单位：Yu. N. Firsova (1)
  S. R. Engel (1)
  N. A. Lozinskaya (1)
  S. E. Sosonyuk (1)
  M. V. Proskurnina (1)
  N. S. Zefirov (1)
  
  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1, Build. 3 Leninskie Gory, 119992, Moscow, Russian Federation
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Organic Chemistry
  Inorganic Chemistry
  Russian Library of Science
  
• 出版者：Springer New York
• ISSN：1573-9171

文摘

The preparative procedure for the synthesis of N-(2,2,2-trichloro-1-hydroxyethyl)aldimines from the corresponding aldehyde, chloral, and ammonium acetate was developed. Preparative silylation and acylation of their hydroxy groups were acomplished for the first time. The possibility to use the synthesized O-trimethylsilyl and O-acetyl derivatives as the synthetic equivalents of N-nonsubstituted imines in the reactions with cyclopropenone was investigated. Keywords 2,2,2-trichloro-1-(arylideneamino)ethanols N-(2,2,2-trichloro-1-hydroxyethyl)aldimines cyclopropenone silylation acylation