High decrease in soil metal bioavailability by metal immobilization with halloysite clay

详细信息    查看全文

• 作者：Joanna Kurczewska ; Piotr Grzesiak ; Joanna ?ukaszyk…
• 关键词：Halloysite Dunino ; Functionalized halloysite ; Heavy metals ; Arsenic ; Soil stabilization ; Sequential extraction
• 刊名：Environmental Chemistry Letters
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：13
• 期：3
• 页码：319-325
• 全文大小：1,735 KB
• 参考文献：Adriano DC, Wenzel WW, Vangronsveld J, Bolan NS (2004) Role of assisted natural remediation in environmental cleanup. Geoderma 122:124-42. doi:10.-016/?j.?geoderma.-004.-1.-03 View Article
  Castaldi P, Santona L, Melis P (2005) Heavy metal immobilization by chemical amendments in a polluted soil and influence on white lupin growth. Chemosphere 60:365-71. doi:10.-016/?j.?chemosphere.-004.-1.-98 View Article
  Grzesiak P, ?ukaszyk J, Schroeder G, Kurczewska J (2013a) Remediation of heavy metals from soil using quartz sand functionalized with organic amino silane. Pol J Chem Technol 15:116-20. doi:10.-478/?pjct-2013-0079
  Grzesiak P, ?ukaszyk J, Grobela M, Kurczewska J, Schroeder G (2013b) Binding of heavy metals and arsenic in soil with N1-(trimethoxysilylpropyl)diethylenetriamine. Przem Chem 92:2115-118
  Grzesiak P, ?ukaszyk J, Schroeder G, Kurczewska J (2014a) Binding of industrial deposits of heavy metals and arsenic in the soil by 3-Aminopropyltrimethoxysilane. Pol J Chem Technol 16:12-5. doi:10.-478/?pjct-2014-0023 View Article
  Grzesiak P, ?ukaszyk J, Kurczewska J, Schroeder G (2014b) The binding of heavy metals and arsenic in the soil by [3-(2-Aminoethylamino)propyl]trimethoxysilane. Pol J Environ Stud 23:961-65
  He Q, Yang D, Deng X, Wu Q, Li R, Zhai Y, Zhang L (2013) Preparation, characterization and application of N-2-Pyridylsuccinamic acid-functionalized halloysite nanotubes for solid-phase extraction of Pb(II). Water Res 47:3976-983. doi:10.-016/?j.?watres.-012.-2.-40 View Article
  Itami K, Yanai J (2006) Sorption and desorption properties of cadmium and copper on soil clays in relation to charge characteristics. Soil Sci Plant Nutr 52:5-2. doi:10.-111/?j.-747-0765.-006.-0015.?x View Article
  Jinhuaa W, Xiang Z, Bing Z, Yafei Z, Rui Z, Jindun L, Rongfeng Ch (2010) Rapid adsorption of Cr(VI) on modified halloysite nanotubes. Desalination 259:22-8. doi:10.-016/?j.?desal.-010.-4.-46 View Article
  Kabata-Pendias A (2004) Soil-plant transfer of trace elements-an environmental issue. Geoderma 122:143-49. doi:10.-016/?j.?geoderma.-004.-1.-04 View Article
  Lombi E, Zhao FJ, Zhang G, Sun B, Fitz W, Zhang H, McGrath SP (2002) In situ fixation of metals in soil using bauxite residue: chemical assessment. Environ Pollut 118:435-43. doi:10.-016/?S0269-7491(01)00294-9 View Article
  Mallampati SR, Mitoma Y, Okuda T, Sakita S, Kakeda M (2013) Total immobilization of soil heavy metals with nano-Fe/Ca/Cao dispersion mixture. Environ Chem Lett 11:119-25. doi:10.-007/?s10311-012-0384-0 View Article
  Tessier A, Campbell PG, Bission M (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal Chem 51:844-51. doi:10.-021/?ac50043a017 View Article
  Wang F, Wang H, Al-Tabbaa A (2014) Leachability and heavy metal speciation of 17-year old stabilized/solidified contaminated site soil. J Hazard Mater 278:144-51. doi:10.-016/?j.?hazmat.-014.-5.-02 View Article
  Wang F, Wang H, Al-Tabbaa A (2015) Time-dependent performance of soil mix technology stabilized/solidified contaminated site soil. J Hazard Mater 286:503-08. doi:10.-016/?j.?hazmat.-015.-1.-07 View Article
  
• 作者单位：Joanna Kurczewska (1)
  Piotr Grzesiak (2)
  Joanna ?ukaszyk (2)
  El?bieta Gaba?a (3)
  Grzegorz Schroeder (1)
  
  1. Faculty of Chemistry, Adam Mickiewicz University in Poznań, Umultowska 89b, 61-614, Poznań, Poland
  2. Department of Ecology and Environmental Protection, Institute of Plant Protection - National Research Institute, W. W?gorka 20, 60-318, Poznań, Poland
  3. The Research Centre of Quarantine, Invasive and Genetically Modified Organisms, Institute of Plant Protection - National Research Institute, W. W?gorka 20, 60-318, Poznań, Poland
  
• 刊物类别：Earth and Environmental Science
• 刊物主题：Earth sciences
  Geochemistry
  Analytical Chemistry
  Biochemistry
  Monitoring, Environmental Analysis and Environmental Ecotoxicology
  Soil Science and Conservation
  Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1610-3661

文摘

Increasing pollution by heavy metals calls for advanced methods to immobilize or extract soil metals, thus avoiding their contact with water, air and living organisms. In particular there is a need for cheap binding materials that extract metals. Here we tested the use of the halloysite clay, functionalized with silanes and non-functionalized, on metal extraction from soils. The clay was functionalized with 3-mercaptopropyl-trimethoxysilane and 3-[2-(2-aminoethylamino)ethylamino]propyltrimethoxysilane. Contaminated soils were sampled at the G?ogów Copper Smelter and Refinery. Soils were sequentially extracted using the Tessier method. Metals were quantified by atomic absorption spectroscopy. Our results show that the addition of halloysite increases the metal content of the plant unavailable fraction that is the fifth fraction of the Tessier method, thus decreasing metal availability. Indeed metal contents of the fifth fraction versus total content increased from 67.64 to 157.79?mg/kg for copper, from 28.10 to 76.14?mg/kg for lead, from 41.60 to 95.78?mg/kg for zinc, from 0.77 to 1.79?mg/kg for cadmium and from 3.96 to 8.90?mg/kg for arsenic.