Enantiomeric composition of polycyclic musks in sediments from the Pearl River and Suzhou Creek

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• 作者：Han Song (1) (2)
  Xiangying Zeng (1)
  Zhiqiang Yu (1)
  Delin Zhang (1) (2)
  Shuxia Cao (1) (3)
  Wenlan Shao (1)
  Guoying Sheng (1)
  Jiamo Fu (1)
  
  1. State Key Laboratory of Organic Geochemistry ; Guangdong Key Laboratory of Environment and Resources ; Guangzhou Institute of Geochemistry ; Chinese Academy of Sciences ; 510640 ; Guangzhou ; China
  2. University of Chinese Academy of Sciences ; 100049 ; Beijing ; China
  3. Material Science Laboratory ; Technologies Development (Dongguan) Co. Ltd ; 523087 ; Dongguan ; China
  
• 关键词：Polycyclic musks ; HHCB ; AHTN ; Enantiomeric composition ; Biotic transformation ; Sediment
• 刊名：Environmental Science and Pollution Research
• 出版年：2015
• 出版时间：February 2015
• 年：2015
• 卷：22
• 期：3
• 页码：1679-1686
• 全文大小：1,123 KB
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• 刊物类别：Earth and Environmental Science
• 刊物主题：Environment
  Environment
  Atmospheric Protection, Air Quality Control and Air Pollution
  Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
  Industrial Pollution Prevention
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1614-7499

文摘

Due to differences in stereostructure, enantiomeric compositions and enantiomeric ratios (ERs) of chiral compounds can be used to discriminate environmental processes such as abiotic and biotic degradation/transformation. In this study, the ERs of two chiral polycyclic musks, 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta(g)-2-benzopyran (HHCB) and 7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene (AHTN), were investigated in the sediments of Zhujiang River and Dongjiang River in the Pearl River Delta (PRD), as well as in those of Suzhou Creek in Shanghai City. The results indicated that ER cis of HHCB varied significantly, ranging from 1.09 to 1.53 and 1.40 to 1.48 in the PRD and Suzhou Creek samples, respectively, whereas ER trans of HHCB exhibited limited variation, ranging from 0.98 to 1.10 and 0.98 to 1.05 for Pearl River and Suzhou Creek samples, respectively. In addition, ERs of AHTN varied substantially from 1.10 to 1.34 and 1.17 to 1.28 in the PRD and Suzhou Creek, respectively. These results suggest that HHCB in the sediment in the study area underwent biotic degradation and the preferential biotransformation isomer was (4R,7S)-HHCB, while AHTN simultaneously underwent a certain degree of biotic degradation/transformation.