Effect of the Molecular Structure on the Adsorption Properties of Cationic Surfactants at the Air–Water Interface

详细信息    查看全文

• 作者：Zineb Lehanine ; Leila Badache
• 关键词：Cationic surfactants ; Isourea ; Counter ion ; Adsorption ; Surface parameters ; Thermodynamic properties
• 刊名：Journal of Surfactants and Detergents
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：19
• 期：2
• 页码：289-295
• 全文大小：517 KB
• 参考文献：1.Kooreman PA, Engberts JBFN, Van Os NM (1998) Synthesis, physicochemical properties, and detergency of disodium 2-alkyl-1,3-propanediyl bissulfates. J Surfactants Deterg 1:23–28CrossRef
  2.Goon P, Bhirud RG, Kumar VV (1999) Detergency and foam studies on linear alkylbenzene sulfonate and secondary alkyl sulfonate. J Surfactants Deterg 2:489–493CrossRef
  3.Schramm LL (2000) Surfactants: fundamentals and applications in the petroleum industry. Cambridge University Press, CambridgeCrossRef
  4.Chappat M (1994) Some applications of emulsions. Colloids Surf A: Physicochem Eng Aspects 91:57–77CrossRef
  5.Farias T, De Menorval LC, Zajac J, Rivera A (2009) Solubilization of drugs by cationic surfactants micelles: conductivity and 1H NMR experiments. Colloids Surf A: Physicochem Eng Aspects 345:51–57CrossRef
  6.Lorente E, Rodríguez A, Aicart E, Junquera E (2007) Non-ionic and cationic micelle nanostructures as drug solubilization vehicles: spectrofluorimetric and electrochemical studies. Colloid Polym Sci 285:1321–1329CrossRef
  7.Itoh Y, Akasaka R (2009) Comparison of surface-active properties of (alkyloxycarbonylmethyl)trimethylammonium chlorides and alkyltrimethylammonium chlorides. J Surfactants Deterg 12:101–107CrossRef
  8.Mishra NC, Müller HJ, Möhwald H, Krastev R (2006) Properties of foam films stabilized with tetraethylammonium perfluorooctane-sulfonate. J Fluor Chem 127:133–139CrossRef
  9.Beneventi D, Carre B, Gandini A (2001) Role of surfactant structure on surface and foaming properties. Colloids Surf A: Physicochem Eng Asp 189:65–73CrossRef
  10.Dopierala K, Prochaska K (2008) The effect of molecular structure on the surface properties of selected quaternary ammonium salts. J Colloid Interface Sci 321:220–226CrossRef
  11.Eastoe J, Nave S, Downer A, Paul A, Rankin A, Tribe K (2000) Adsorption of ionic surfactants at the air-solution interface. Langmuir 16:4511–4518CrossRef
  12.Knock MM, Bain CD (2000) Effect of counterion on monolayers of hexadecyltrimethylammonium halides at the air–water interface. Langmuir 16:2857–2865CrossRef
  13.Lehmler HJ, Oyewumi MO, Jay M, Bummer PM (2001) Behavior of partially fluorinated carboxylic acids at the air–water interface. J Fluor Chem 107:141–146CrossRef
  14.Vollhardt D, Czichocki G, Rudert R (1998) Effect of the molecular structure on the adsorption of alkyl ether sulphates and alkane ether sulphonates at the air–water interface. Colloids Surf A: Physicochem Eng Asp 142:315–322CrossRef
  15.Rosen MJ, Dahanayake M, Cohen AW (1982) Relation of structure to properties in surfactants. 11. Surface and thermodynamic properties of N-dodecyl-pyridinium bromide and chloride. Colloids Surf 5:159–172CrossRef
  16.Tan X, Zhang L, Zhao S, Yu J, An J (2004) Synthesis and study of the surface properties of long-chain alkylnaphthalene sulfonates. J Surfactants Deterg 7:135–139CrossRef
  17.Zhu YP, Rosen MJ, Morrall SW (1998) Chemical structure/property relationships in surfactants. 17. N-substituted-N-acyl glycinates in pure and synthetic hard river water. J Surfactants Deterg 1:1–9CrossRef
  18.Badache L, Boschet F, Lehanine Z, Boutevin B, Ameduri B (2011) Synthesis and surface properties of a series of surfactants based on O-alkyl and O-perfluoro-N,N′-diisopropylisoureas. J Fluor Chem 123:382–388CrossRef
  19.Lehanine Z, Badache L (2011) Thermodynamics of micellization of cationic surfactants based on O-alkyl and O-perfluoro-N,N′-diisopropylisoureas. J Chem Thermodyn 43:1342–1348CrossRef
  20.Rosen MJ (2004) Surfactants and interfacial phenomena, 3rd edn. Wiley, New YorkCrossRef
  21.Asadov ZH, Rahimov RA, Nasibova SM, Ahmadova GA (2010) Surface activity, thermodynamics of micellization and adsorption properties of quaternary salts based on ethanolamines and decyl bromide. J Surfactants Deterg 13:459–464CrossRef
  22.Shimizu S, El Seoud OA (2003) 2-(Acylaminoethyl)trimethylammonium chloride surfactants: synthesis and properties of aqueous solutions. Colloid Polym Sci 282:21–31CrossRef
  23.Gad EAM, Badawi AM, Zaki M (1999) Surface and thermodynamic studies of N-Alkyl N-trimethylsilane ammonium chloride surfactants. J Surfactants Deterg 2:45–50CrossRef
  24.Fainerman VB, Miller R, Aksenenko EV, Makievski AV, Krägel J, Loglio G, Liggieri L (2000) Effect of surfactant interfacial orientation/aggregation on adsorption dynamics. Adv Colloid Interface Sci 86:83–101 CrossRef
  
• 作者单位：Zineb Lehanine (1)
  Leila Badache (1)
  
  1. Laboratoire de Chimie Organique Appliquée, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene, BP 32, El-Alia - Bab Ezzouar, 16111, Algiers, Algeria
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Industrial Chemistry and Chemical Engineering
  Surfaces and Interfaces and Thin Films
  Polymer Sciences
  Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
  Analytical Chemistry
  Physical Chemistry
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1558-9293

文摘

The surface activity and thermodynamic properties of adsorption at the air–water interface of two series of cationic surfactants based on isourea: the O-dodecyl-N,N′-diisopropylisourea hydrochloride, hydrobromide, and hydroiodide and the O-tridecafluorooctyl-N,N′-diisopropylisourea hydrochloride and hydrobromide were studied. The effect of structural parameters as the nature of the halide counter ion and the nature of the non-polar chain on the surface activity and thermodynamic properties of adsorption were investigated. The surface parameters, the maximum surface excess concentration (Γ _max), the minimum area per molecule (A _min) at the aqueous solution-air interface, effectiveness of surface tension reduction (π_CMC), and efficiency of surface tension reduction (pC ₂₀) were estimated. The standard Gibbs free energy of adsorption, (ΔG°_ads) change has been calculated at different temperatures.