A sensitive analytical procedure?for monitoring acrylamide in environmental water samples by offline SPE–UPLC/MS/MS

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• 作者：Anne Togola ; Charlotte Coureau…
• 关键词：Acrylamide ; Analysis ; SPE ; LC/MS/MS ; Groundwater ; Process water ; Surface water
• 刊名：Environmental Science and Pollution Research
• 出版年：2015
• 出版时间：May 2015
• 年：2015
• 卷：22
• 期：9
• 页码：6407-6413
• 全文大小：433 KB
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• 作者单位：Anne Togola (1)
  Charlotte Coureau (1)
  Anne-Gwena?lle Guezennec (1)
  Solène Touzé (1)
  
  1. Bureau de recherches géologiques et minières (BRGM), 3 avenue Claude Guillemin, 45100, Orléans, France
  
• 刊物类别：Earth and Environmental Science
• 刊物主题：Environment
  Environment
  Atmospheric Protection, Air Quality Control and Air Pollution
  Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
  Industrial Pollution Prevention
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1614-7499

文摘

The presence of acrylamide in natural systems is of concern from both environmental and health points of view. We developed an accurate and robust analytical procedure (offline solid phase extraction combined with UPLC/MS/MS) with a limit of quantification (20?ng?L?) compatible with toxicity threshold values. The optimized (considering the nature of extraction phases, sampling volumes, and solvent of elution) solid phase extraction (SPE) was validated according to ISO Standard ISO/IEC 17025 on groundwater, surface water, and industrial process water samples. Acrylamide is highly polar, which induces a high variability during the SPE step, therefore requiring the use of C13-labeled acrylamide as an internal standard to guarantee the accuracy and robustness of the method (uncertainty about 25?% (k--) at limit of quantification level). The specificity of the method and the stability of acrylamide were studied for these environmental media, and it was shown that the method is suitable for measuring acrylamide in environmental studies.