New Progress in Monomeric Phthalocyanine Chemistry: Synthesis, Crystal Structures and Properties

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• 作者：Zhonghai Ni ; Renjie Li ; Jianzhuang Jiang
• 关键词：Crystal structure ; Modification ; Phthalocyanine ; Property ; Synthesis
• 刊名：Structure & Bonding
• 出版年：2009
• 出版时间：2009
• 年：2009
• 卷：133
• 期：1
• 页码：121-160
• 全文大小：2.4 MB

文摘

In this chapter, recent progress in the synthesis, crystal structures and physical properties of monomeric phthalocyanines (Pcs) is summarized and analysed. The strategies for synthesis and modification of Pcs include axial coordination of central metal ions, peripheral substitution of Pc rings and the ionization of Pcs. The crystal structures of various typical Pcs, especially the effects of different synthetic and modification strategies on the supramolecular assemblies of Pcs via π–π interactions between Pc rings, are discussed in detail. Finally, the UV–vis spectroscopic, conducting, magnetic and catalytic properties of some Pcs with crystal structures are presented briefly, and the correlations between various properties and the molecular structure discussed.