Improved conversion efficiency of dye-sensitized solar cells by using novel complex nanostructured TiO2 electrodes
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  • 作者:TianShu Zhang (1)
    LiFeng Liu (1)
    Fei Yang (1)
    Yi Wang (1)
    JinFeng Kang (1)
  • 关键词:dye ; sensitized solar cells ; conversion efficiency ; nanoporous TiO2 electrode ; anodization
  • 刊名:SCIENCE CHINA Technological Sciences
  • 出版年:2013
  • 出版时间:January 2013
  • 年:2013
  • 卷:56
  • 期:1
  • 页码:115-119
  • 全文大小:823KB
  • 参考文献:1. O’Regan B, Gr?tzel B. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 1991, 353: 737-40 CrossRef
    2. Gr?tzel M. Photoelectrochemical cells. Nature, 2001, 414: 338-44 CrossRef
    3. Chiba Y, Islam A, Watanabe Y, et al. Dye-sensitized solar cells with conversion efficiency of 11.1%. Jpn J Appl Phys, 2006, 45: L638–L640 CrossRef
    4. Hu L, Dai S, Weng J, et al. Microstructure design of nanoporous TiO2 photoelectrodes for dye-sensitized solar cell modules. J Phys Chem B, 2007, 111: 358-62 CrossRef
    5. Jiu J, Isoda S, Adachi M, et al. Preparation of TiO2 nanocrystalline with 3-5 nm and application for dye-sensitized solar cell. J Photoch Photobio A, 2007, 189: 314-21 CrossRef
    6. Zhou Y F, Li X P, Zhang J B, et al. Performances improvement of eosin Y sensitized solar cells by modifying TiO2 electrode with silane-coupling reagent. Chin Sci Bull, 2009, 54: 2633-640 CrossRef
    7. Nguyen T V, Lee H C, Yang O. The effects of pre-thermal treatment of TiO2 nano-particles on the performances of dye-sensitized solar cells. Sol Energ Mat Sol C, 2006, 90: 967-81 CrossRef
    8. Gr?tzel M. Dye-sensitized solar cells. J Photoch Photobio C, 2003, 4: 145-53 CrossRef
    9. Ma B B, Gao R, Wang L D, et al. Recent progress in interface modification for dye-sensitized solar cells. Sci China Chem, 2010, 53: 1669-678 CrossRef
    10. Law M, Greene L E, Johnson J C, et al. Nanowire dye-sensitized solar cells. Nat Mater, 2005, 4: 455-59 CrossRef
    11. Mor G K, Shankar K, Paulose M, et al. Enhanced photocleavage of water using titania nanotube arrays. Nano Lett, 2005, 5: 191-95 CrossRef
    12. Yoon J H, Jang S R, Vittal R, et al. TiO2 nanorods as additive to TiO2 film for improvement in the performance of dye-sensitized solar cells. J Photochem Photobiol A, 2006, 180: 184-88 CrossRef
    13. Luo J Q, Gao L, Sun J, et al. A bilayer structure of a titania nanoparticle/ highly-ordered nanotube array for low-temperature dye-sensi-tized solar cells. RSC Adv, 2012, 2: 1884-889 CrossRef
    14. Miao Q Q, Wu L Q, Cui J N, et al. A new type of dye-sensitized solar cell with a multilayered photoanode prepared by a film-transfer technique. Adv Mater, 2011, 23: 2764-768 CrossRef
    15. Wang H, Liu Y, Li M, et al. Hydrothermal growth oflarge-scale macroporous TiO2 nanowires and its application in 3D dye sensitized solar cells. Appl Phys A, 2009, 97: 25-9 CrossRef
    16. Tsai T Y, Lu S Y. A novel way of improving light harvesting in dye-sensitized solar cells-electrodeposition of titania. Electrochem Commun, 2009, 11: 2180-183 CrossRef
    17. Kang T S, Smith A P, Taylor B E, et al. Fabrication of highly-ordered TiO2 nanotube arrays and their use in dye-sensitized solar cells. Nano Lett, 2009, 9: 601-06 CrossRef
    18. Wang C X, Zhang X D, Wang D F, et al. Synthesis of nanostructural ZnO using hydrothermal method for dye-sensitized solar cells. Sci China Tech Sci, 2010, 53: 1146-149 CrossRef
  • 作者单位:TianShu Zhang (1)
    LiFeng Liu (1)
    Fei Yang (1)
    Yi Wang (1)
    JinFeng Kang (1)

    1. Institute of Microelectronics, Peking University, Beijing, 100871, China
  • ISSN:1869-1900
文摘
A novel complex nanostructured TiO2 electrode and fabrication process were proposed and demonstrated to improve the performance of dye-sensitized solar cells (DSSCs). In the proposed process, a nanoporous TiO2 layer was firstly fabricated on the FTO (fluorine-doped tin oxide) conducting substrate by an anodization process, then a nanoparticulate TiO2 film was deposited on the nanoporous TiO2 layer by the screen printed method to form the complex nanostructured TiO2 electrode. The experiments demonstrated that the nanoporous TiO2 layer can enhance the light scattering, decrease the contact resistance between TiO2 electrode and FTO, and suppress the recombination of I 3 ?/sup> ion with the injected electrons of FTO. The process variables are crucial to obtain the optimized performance of DSSCs. By adopting the optimized process, improved conversion efficiency of DSSCs was achieved at AM 1.5 sunlight.

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